Reck, G., Schierhorn, E., Müller, J.-T., Mühlberg, M. (1995) Crystal structures of two nitroprussides: SmNa[Fe(CN)5NO]2 · 7H2O and GdNa[Fe(CN)5NO]2 · 7H2O. Zeitschrift für Kristallographie - Crystalline Materials, 210 (10) 754 doi:10.1524/zkri.1995.210.10.754
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Crystal structures of two nitroprussides: SmNa[Fe(CN)5NO]2 · 7H2O and GdNa[Fe(CN)5NO]2 · 7H2O | ||
| Journal | Zeitschrift für Kristallographie - Crystalline Materials | ||
| Authors | Reck, G. | Author | |
| Schierhorn, E. | Author | ||
| Müller, J.-T. | Author | ||
| Mühlberg, M. | Author | ||
| Year | 1995 (January 1) | Volume | 210 |
| Issue | 10 | ||
| Publisher | Walter de Gruyter GmbH | ||
| DOI | doi:10.1524/zkri.1995.210.10.754Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 114534 | Long-form Identifier | mindat:1:5:114534:6 |
| GUID | 0 | ||
| Full Reference | Reck, G., Schierhorn, E., Müller, J.-T., Mühlberg, M. (1995) Crystal structures of two nitroprussides: SmNa[Fe(CN)5NO]2 · 7H2O and GdNa[Fe(CN)5NO]2 · 7H2O. Zeitschrift für Kristallographie - Crystalline Materials, 210 (10) 754 doi:10.1524/zkri.1995.210.10.754 | ||
| Plain Text | Reck, G., Schierhorn, E., Müller, J.-T., Mühlberg, M. (1995) Crystal structures of two nitroprussides: SmNa[Fe(CN)5NO]2 · 7H2O and GdNa[Fe(CN)5NO]2 · 7H2O. Zeitschrift für Kristallographie - Crystalline Materials, 210 (10) 754 doi:10.1524/zkri.1995.210.10.754 | ||
| In | (1995, January) Zeitschrift für Kristallographie - Crystalline Materials Vol. 210 (10) Walter de Gruyter GmbH | ||
| Abstract/Notes | AbstractSamarium sodium bis(nitrosylpentacyanoferrate-(II)) heptahydrate/(I) crystallizes in space groupGadolinium sodium bis(nitrosylpentacyanoferrate-(II))heptahydrate/(II) crystallizes in space groupIn both isomorphous structures the iron atoms are coordinated to five cyanide ligands and one nitrosyl group, while the sodium atoms are coordinated to four cyanide groups and two water molecules. Both centres have distorted octahedral symmetries. The coordination sphere of the second cation, samarium and gadolinium, respectively, consists of four cyanide groups and five water molecules. Cyanide bridges connect the iron, sodium, and the samarium/gadolinium polyhedrons forming sinusoidal layers. | ||
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