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Rotzinger, Francois P. (1988) Base hydrolysis of pentaammine complexes of cobalt(III): structure, reactivity, and lifetime of the intermediates. Inorganic Chemistry, 27 (5) 772-776 doi:10.1021/ic00278a005

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Reference TypeJournal (article/letter/editorial)
TitleBase hydrolysis of pentaammine complexes of cobalt(III): structure, reactivity, and lifetime of the intermediates
JournalInorganic Chemistry
AuthorsRotzinger, Francois P.Author
Year1988 (March)Volume27
Issue5
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ic00278a005Search in ResearchGate
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Mindat Ref. ID1432341Long-form Identifiermindat:1:5:1432341:6
GUID0
Full ReferenceRotzinger, Francois P. (1988) Base hydrolysis of pentaammine complexes of cobalt(III): structure, reactivity, and lifetime of the intermediates. Inorganic Chemistry, 27 (5) 772-776 doi:10.1021/ic00278a005
Plain TextRotzinger, Francois P. (1988) Base hydrolysis of pentaammine complexes of cobalt(III): structure, reactivity, and lifetime of the intermediates. Inorganic Chemistry, 27 (5) 772-776 doi:10.1021/ic00278a005
In(1988, March) Inorganic Chemistry Vol. 27 (5) American Chemical Society (ACS)

See Also

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Rotzinger, Francois P. (1988) Kinetics of base hydrolysis of (nitrato)pentaamminecobalt(III): stability and reactivity of its ion pairs with perchlorate and azide. Inorganic Chemistry, 27 (5) 768-771 doi:10.1021/ic00278a004
Rotzinger, Francois P. (1991) Base hydrolysis of acidato pentakis(methylamine) complexes of cobalt(III): evidence for the pentacoordinated intermediate Co(NH2CH3)4(NHCH3)2+ exhibiting a lifetime of .apprxeq. 1 ns. Inorganic Chemistry, 30 (13) 2763-2772 doi:10.1021/ic00013a012
Rotzinger, Francois P., Marty, Werner (1983) Activated ligand substitution in bridged complexes. 1. Base hydrolysis and structure of (.+-.)-(.mu.-amido)-cis,cis-tetrakis(1,2-ethanediamine)diamminedicobalt(III) pentanitrate dihydrate. Inorganic Chemistry, 22 (24) 3593-3602 doi:10.1021/ic00166a022
Rotzinger, Fran�ois P., Weber, Jacques, Daul, Claude (1991) Base Hydrolysis of (Acidato)(Pentaamine) Complexes with Inert Metal Centers: Electronic Structure of the Intermediates, Requirements for Their Formation, and the Unique Reactivity of the Complexes of Cobalt(III). Helvetica Chimica Acta, 74 (6). 1247-1263 doi:10.1002/hlca.19910740613
Rotzinger, François P. (1999) Aquation of the Chloro Pentaammine Complexes of Cobalt(III) and Chromium(III):  Do the Almost Equal Activation Parameters Arise from a Common Mechanism?. Inorganic Chemistry, 38 (25) 5730-5733 doi:10.1021/ic990748m
Rotzinger, François P., Benoit, David M. (2000) Mechanism of the S → N Isomerization and Aquation of the Thiocyanato Pentaammine Cobalt(III) Ion. Inorganic Chemistry, 39 (5) 944-952 doi:10.1021/ic990948y
Curchod, Basile F. E., Rotzinger, François P. (2011) The Cause for Tremendous Acceleration of Chloride Substitution via Base Catalysis in the Chloro Pentaammine Cobalt(III) Ion. Inorganic Chemistry, 50 (18) 8728-8740 doi:10.1021/ic102034n
Rotzinger, Francois P., Mueller, Edgar, Marty, Werner (1987) Activated ligand substitution in bridged complexes. 2. Base hydrolysis of the (.mu.-amido)decaamminedicobalt(5+) ion. Synthesis and structure of (.mu.-amido)chloroenneaamminedicobalt(4+) ion. Inorganic Chemistry, 26 (24) 3989-3994 doi:10.1021/ic00271a006
Jordan, R. B., Sargeson, A. M. (1965) Five-Coordinate Intermediates in the Base Hydrolysis of Cobalt(III) Complexes. Inorganic Chemistry, 4 (3) 433-434 doi:10.1021/ic50025a048
Grančičová, Ol'ga, Fabulová, Ivana (1992) Base hydrolysis of pentaammine complexes of cobalt(III) in aqueous-organic mixed solvents. Transition Metal Chemistry, 17 (3). 190-195 doi:10.1007/bf02910834
House, Donald A. (1988) Kinetics of the base hydrolysis of chloro(diamine)(triamine)chromium(III) complexes: evidence for the SN1CB mechanism in chromium(III) polyamine complexes. Inorganic Chemistry, 27 (15) 2587-2591 doi:10.1021/ic00288a007
 
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