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Challen, P. R., Koo, Sang Man, Kim, C. G., Dunham, W. R., Coucouvanis, D. (1990) Nitrogenase substrates as intercluster bridging units between the molybdenum atoms in doubly bridged, double cubanes. The synthesis and characterization of the [MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)(.mu.2-L)]n- anions (L = N2H4, n = 4; L = CN-, n = 5) Journal Of The American Chemical Society, 112 (23) 8606-8607 doi:10.1021/ja00179a068

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Reference TypeJournal (article/letter/editorial)
TitleNitrogenase substrates as intercluster bridging units between the molybdenum atoms in doubly bridged, double cubanes. The synthesis and characterization of the [MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)(.mu.2-L)]n- anions (L = N2H4, n = 4; L = CN-, n = 5)
JournalJournal Of The American Chemical Society
AuthorsChallen, P. R.Author
Koo, Sang ManAuthor
Kim, C. G.Author
Dunham, W. R.Author
Coucouvanis, D.Author
Year1990 (November)Volume112
Issue23
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja00179a068Search in ResearchGate
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Mindat Ref. ID1444771Long-form Identifiermindat:1:5:1444771:6
GUID0
Full ReferenceChallen, P. R., Koo, Sang Man, Kim, C. G., Dunham, W. R., Coucouvanis, D. (1990) Nitrogenase substrates as intercluster bridging units between the molybdenum atoms in doubly bridged, double cubanes. The synthesis and characterization of the [MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)(.mu.2-L)]n- anions (L = N2H4, n = 4; L = CN-, n = 5) Journal Of The American Chemical Society, 112 (23) 8606-8607 doi:10.1021/ja00179a068
Plain TextChallen, P. R., Koo, Sang Man, Kim, C. G., Dunham, W. R., Coucouvanis, D. (1990) Nitrogenase substrates as intercluster bridging units between the molybdenum atoms in doubly bridged, double cubanes. The synthesis and characterization of the [MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)(.mu.2-L)]n- anions (L = N2H4, n = 4; L = CN-, n = 5) Journal Of The American Chemical Society, 112 (23) 8606-8607 doi:10.1021/ja00179a068
In(1990, November) Journal Of The American Chemical Society Vol. 112 (23) American Chemical Society (ACS)

See Also

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Coucouvanis, Dimitri, Challen, P. R., Koo, Sang Man, Davis, W. M., Butler, W., Dunham, W. R. (1989) Stepwise synthesis and structural characterization of the molybdenum-iron-sulfur {[MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)2}6- and {[MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)(.mu.2-OH}5- doubly bridged double cubanes obtained by the coupling of [MoFe3S4] clusters. Inorganic Chemistry, 28 (23) 4181-4183 doi:10.1021/ic00322a001
Challen, P. R., Koo, Sang Man, Dunham, W. R., Coucouvanis, D. (1990) New .mu.2-S2--coupled, singly bridged double cubane with the [(Fe4S4Cl3)2S]4- core. The stepwise synthesis and structural characterization of (n-Bu4N)2(Ph4P)2[(Fe4S4Cl3)2S]. Journal Of The American Chemical Society, 112 (6) 2455-2456 doi:10.1021/ja00162a076
Coucouvanis, Dimitri, Demadis, Konstantinos D., Kim, Chang G., Dunham, Richard W., Kampf, Jeff W. (1993) Single and double MoFe3S4 cubanes with molybdenum-coordinated polycarboxylate ligands. Syntheses and structural characterization of (Et4N)4{[MoFe3S4Cl4]2(.mu.-C2O4)} and (Et4N)3([MoFe3S4Cl4(C2O4)] clusters. Journal Of The American Chemical Society, 115 (8) 3344-3345 doi:10.1021/ja00061a049
Coucouvanis, D., Toupadakis, A., Lane, J. D., Koo, S. M., Kim, C. G., Hadjikyriacou, A. (1991) Reactivity of the Mo(O)(S) functional group in the [(L)Mo(O)(.mu.-S)2Mo(O)(S)]n- dimeric thiomolybdate complexes, (L = C5H5-, n = 1; S42-, n = 2) and implications regarding the function of xanthine oxidase. Synthesis and structural characterization of [(DMF)3Mo(O)(.mu.-S)2Mo(O)(S2)], [Ph4P][(C5H5)Mo(O)(.mu.-S)2Mo(O)(S2)], [Ph4P]2[(S4)Mo(O)(.mu.-S)2Mo(O)(S)] and (Et4N)4{[(S4)Mo(O)(.mu.-S)2Mo(O)(S)]2}. Journal Of The American Chemical Society, 113 (14) 5271-5282 doi:10.1021/ja00014a021
Coucouvanis, D., Swenson, D., Baenziger, N. C., Pedelty, R., Caffery, M. L., Kanodia, S. (1989) Protonation of the 1,1-dithiolene ligands in the [Cu8(L)6]4- cubanes (L = [S2C:C(COOR)2]2-) and synthesis of the [Cu8(L)6-n(H-L)n]-(4-n) clusters. Synthesis and structural characterization of the [Cu10(H-L)6(L)2] decanuclear cluster. Inorganic Chemistry, 28 (14) 2829-2836 doi:10.1021/ic00313a028
Coucouvanis, D., Al-Ahmad, Saleem, Kim, C. G., Mosier, P. E., Kampf, J. W. (1993) Oxidative decoupling of the molybdenum-iron-sulfur MoFe3S4 clusters and possible relevance to the oxidative degradation of the nitrogenase cofactor. Isolation and structural characterization of the [(Cl4cat)Mo(O)(.mu.-S)2FeCl2]2- anion. Inorganic Chemistry, 32 (9) 1533-1535 doi:10.1021/ic00061a001
Coucouvanis, D., Reynolds, R. A., Dunham, W. R. (1995) Synthesis and Characterization of a New Class of Asymmetric Aqua-Acetate Bridged Dimers. Solid State Molecular Structures of the [M2(.mu.-H2O)(.mu.-OAc)2(OAc)3(Py)2]- Anions (M = Mn(II), Fe(II), Co(II)) A Structural Model for the Fe2 Site in Methane Monooxygenase. Journal Of The American Chemical Society, 117 (28) 7570-7571 doi:10.1021/ja00133a041
Coucouvanis, D., Salifoglou, A., Kanatzidis, M. G., Dunham, W. R., Simopoulos, A., Kostikas, A. (1988) Synthesis, structural characterization, and electronic properties of the [(Fe6S6X6)(M(CO)3)2]n- anions (M = Mo, W; n = 3, 4; X = Cl, Br, I) Heteronuclear clusters of possible structural relevance to the iron-molybdenum-sulfur center in nitrogenase. Inorganic Chemistry, 27 (22) 4066-4077 doi:10.1021/ic00295a034
Coucouvanis, D., Baenziger, N. C., Simhon, E. D., Stremple, P., Swenson, D., Simopoulos, A., Kostikas, A., Petrouleas, V., Papaefthymiou, V. (1980) Synthesis and structural characterization of the (Ph4P)2[Cl2FeS2MS2FeCl2] complexes (M = molybdenum, tungsten) First example of a doubly bridging thiomolybdate (MoS4) unit and its possible relevance as a structural feature in the nitrogenase active site. Journal Of The American Chemical Society, 102 (5) 1732-1734 doi:10.1021/ja00525a050
Coucouvanis, D., Koo, Sang Man (1989) Rational synthesis of monooxo thioanions from tetrakis(benzenethiolato)oxomolybdate(1-) Structural characterization of the [Ph4P]+ salts of the [(.eta.2-S2)MoO(.mu.-S)2MoS(.eta.2-S2)]2-, [(.eta.2-S2)MoO(MoS4)]2-, [(S4)MoX(.mu.-S)2MoSX(.eta.2-S2)]2- (X = S, O), and [(S4)MoO(MoS4)]2- anions. Inorganic Chemistry, 28 (1) 2-5 doi:10.1021/ic00300a002
Al-Ahmad, S. A., Salifoglou, A., Kanatzidis, M. G., Dunham, W. R., Coucouvanis, D. (1990) Octanuclear heterometallic clusters with rhombic dodecahedral cores. The synthesis, structural characterization, and properties of the [Fe6S6(p-RPhO)6[M(CO3]2]n- clusters (M = Mo, n = 3, R = Me, OMe, N(Me2); M = W, n = 3, R = Me; M = Mo, n = 4, R = Me, OMe, COMe) Precursors for synthetic analogs for the Fe/Mo/S site in nitrogenase. Inorganic Chemistry, 29 (5) 927-938 doi:10.1021/ic00330a007
 
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