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Gagné, Olivier, Hawthorne, Frank, Shannon, Robert D., Fischer, Reinhard X. (2018) Empirical electronic polarizabilities: deviations from the additivity rule. I. M2+SO4·nH2O, blödite Na2M2+(SO4)2·4H2O, and kieserite-related minerals with sterically strained structures. Physics and Chemistry of Minerals, 45 (3) 303-310 doi:10.1007/s00269-017-0919-9

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Reference TypeJournal (article/letter/editorial)
TitleEmpirical electronic polarizabilities: deviations from the additivity rule. I. M2+SO4·nH2O, blödite Na2M2+(SO4)2·4H2O, and kieserite-related minerals with sterically strained structures
JournalPhysics and Chemistry of Minerals
AuthorsGagné, OlivierAuthor
Hawthorne, FrankAuthor
Shannon, Robert D.Author
Fischer, Reinhard X.Author
Year2018 (March)Volume45
Issue3
PublisherSpringer Science and Business Media LLC
DOIdoi:10.1007/s00269-017-0919-9Search in ResearchGate
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Mindat Ref. ID154231Long-form Identifiermindat:1:5:154231:2
GUID0
Full ReferenceGagné, Olivier, Hawthorne, Frank, Shannon, Robert D., Fischer, Reinhard X. (2018) Empirical electronic polarizabilities: deviations from the additivity rule. I. M2+SO4·nH2O, blödite Na2M2+(SO4)2·4H2O, and kieserite-related minerals with sterically strained structures. Physics and Chemistry of Minerals, 45 (3) 303-310 doi:10.1007/s00269-017-0919-9
Plain TextGagné, Olivier, Hawthorne, Frank, Shannon, Robert D., Fischer, Reinhard X. (2018) Empirical electronic polarizabilities: deviations from the additivity rule. I. M2+SO4·nH2O, blödite Na2M2+(SO4)2·4H2O, and kieserite-related minerals with sterically strained structures. Physics and Chemistry of Minerals, 45 (3) 303-310 doi:10.1007/s00269-017-0919-9
In(2018, March) Physics and Chemistry of Minerals Vol. 45 (3) Springer Science and Business Media LLC

See Also

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Shannon, Robert D., Kabanova, Natalia A., Fischer, Reinhard X. (2019) Empirical Electronic Polarizabilities: Deviations from the Additivity Rule. II. Structures Exhibiting Ion Conductivity. Crystal Research and Technology, 54 (7) doi:10.1002/crat.201900037
Burianek, Manfred, Birkenstock, Johannes, Mair, Philipp, Kahlenberg, Volker, Medenbach, Olaf, Shannon, Robert D., Fischer, Reinhard X. (2016) High-pressure synthesis, long-term stability of single crystals of diboron trioxide, B2O3, and an empirical electronic polarizability of [3]B3+. Physics and Chemistry of Minerals, 43 (7) 527-534 doi:10.1007/s00269-016-0813-x
Shannon, Robert D., Fischer, Reinhard X. (2006) Empirical electronic polarizabilities in oxides, hydroxides, oxyfluorides, and oxychlorides. Physical Review B, 73 (23) doi:10.1103/physrevb.73.235111
(2019) Ion Conductivity: Empirical Electronic Polarizabilities: Deviations from the Additivity Rule. II. Structures Exhibiting Ion Conductivity (Crystal Research and Technology 7/2019) Crystal Research and Technology, 54 (7) doi:10.1002/crat.201970022
Volkova, L. M., Marinin, D. V. (2018) Spin-frustrated pyrochlore chains in the volcanic mineral kamchatkite (KCu3OCl(SO4)2) Physics and Chemistry of Minerals, 45 (7) 655-668 doi:10.1007/s00269-018-0950-5
Fortes, A. D., Knight, K. S., Gibbs, A. S., Wood, I. G. (2018) Crystal structures of NiSO4·9H2O and NiSO4·8H2O: magnetic properties, stability with respect to morenosite (NiSO4·7H2O), the solid-solution series (MgxNi1−x)SO4·9H2O. Physics and Chemistry of Minerals, 45 (8) 695-712 doi:10.1007/s00269-018-0956-z
Shannon, Robert D., Fischer, Reinhard X. (2016) Empirical electronic polarizabilities of ions for the prediction and interpretation of refractive indices: Oxides and oxysalts. American Mineralogist, 101 (10) 2288-2300 doi:10.2138/am-2016-5730
Nazzareni, S., Comodi, P., Hanfland, M. (2018) High-pressure single-crystal synchrotron X-ray diffraction of kainite (KMg(SO4) Cl 3H2O) Physics and Chemistry of Minerals, 45 (8) 727-743 doi:10.1007/s00269-018-0958-x
Members of the blödite group are hydrated sulfates with the basic formula Na2M2+(SO4)2 • 4H2O, in which the M2 site can be occupied by a range of bivalent metal cations. In blödite as originally described, this site is occupied by Mg, and the crystals are generally colorless. At the Blue Lizard Mine in Utah, by contrast, two additional species have been described in which the M2 site is filled by Mn (manganoblödite) or Co (cobaltoblödite), with the crystal aggregates having varying degrees of pinkish to reddish coloration (Kasatkin et al. 2013). As noted by these authors, at the type-locality: “…both minerals are intimately intergrown with each other and Mn-Co-Ni-bearing blödite…The three minerals cannot be distinguished from one another by visual methods
Majzlan, Juraj, Marinova, Delyana, Dachs, Edgar (2021) Thermodynamics of the double sulfates Na2M2+(SO4)2·nH2O (M = Mg, Mn, Co, Ni, Cu, Zn, n = 2 or 4) of the blödite–kröhnkite family. RSC Advances, 11 (1) 374-379 doi:10.1039/d0ra09501j
Fischer, Reinhard X., Burianek, Manfred, Shannon, Robert D. (2020) Determination of the H2O content in minerals, especially zeolites, from their refractive indices based on mean electronic polarizabilities of cations. European Journal of Mineralogy, 32 (1) 27-40 doi:10.5194/ejm-32-27-2020
 
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