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Hughes, Russell P., Smith, Jeremy M. (1999) Hydrogenolysis of Aliphatic Carbon−Fluorine Bonds in Fluoroalkyl−Iridium Complexes to Give Hydrofluorocarbons. Journal Of The American Chemical Society, 121 (25) 6084-6085 doi:10.1021/ja990490z

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Reference TypeJournal (article/letter/editorial)
TitleHydrogenolysis of Aliphatic Carbon−Fluorine Bonds in Fluoroalkyl−Iridium Complexes to Give Hydrofluorocarbons
JournalJournal Of The American Chemical Society
AuthorsHughes, Russell P.Author
Smith, Jeremy M.Author
Year1999 (June)Volume121
Issue25
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja990490zSearch in ResearchGate
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Mindat Ref. ID1546721Long-form Identifiermindat:1:5:1546721:2
GUID0
Full ReferenceHughes, Russell P., Smith, Jeremy M. (1999) Hydrogenolysis of Aliphatic Carbon−Fluorine Bonds in Fluoroalkyl−Iridium Complexes to Give Hydrofluorocarbons. Journal Of The American Chemical Society, 121 (25) 6084-6085 doi:10.1021/ja990490z
Plain TextHughes, Russell P., Smith, Jeremy M. (1999) Hydrogenolysis of Aliphatic Carbon−Fluorine Bonds in Fluoroalkyl−Iridium Complexes to Give Hydrofluorocarbons. Journal Of The American Chemical Society, 121 (25) 6084-6085 doi:10.1021/ja990490z
In(1999, June) Journal Of The American Chemical Society Vol. 121 (25) American Chemical Society (ACS)

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Hughes, Russell P., Smith, Jeremy M., Incarvito, Christopher D., Lam, Kin-Chun, Rhatigan, Brian, Rheingold, Arnold L. (2002) Cationic Iridium−Perfluoroalkyl Complexes with NH3and PH3Ligands. Activation of Carbon−Fluorine Bonds by H2S To Give Bis(trifluoromethyl)dithiametallacyclobutane and Bis(trifluoromethyl)trithiametallacyclohexane Complexes. Organometallics, 21. 2136-2144 doi:10.1021/om0200407
Hughes, Russell P., Smith, Jeremy M., Incarvito, Christopher D., Lam, Kin-Chun, Rhatigan, Brian, Rheingold, Arnold L. (2004) Cationic Iridium−Perfluoroalkyl Complexes with NH3and PH3Ligands. Activation of Carbon−Fluorine Bonds by H2S To Give Bis(trifluoromethyl)dithiametallacyclobutane and Bis(trifluoromethyl)trithiametallacyclohexane Complexes. Organometallics, 23. 3362 doi:10.1021/om040066t
Hughes, Russell P., Willemsen, Stefan, Williamson, Alex, Zhang, Donghui (2002) Carbon−Fluorine Bond Hydrogenolysis in Perfluoroethyl−Iridium Complexes To Give HFC-134a Involves Heterolytic Activation of H2. Organometallics, 21. 3085-3087 doi:10.1021/om020225d
Hughes, Russell P., Lindner, Danielle C., Rheingold, Arnold L., Liable-Sands, Louise M. (1997) Facile Activation of Carbon−Fluorine Bonds in Saturated Fluoroalkyl Ligands by Coordinated Water in Fluoroalkyl Aqua Complexes of Rhodium. Journal Of The American Chemical Society, 119 (47) 11544-11545 doi:10.1021/ja9723388
Hughes, Russell P., Larichev, Roman B., Zakharov, Lev. N., Rheingold, Arnold L. (2006) Carbon−Fluorine Bond Activation Coupled with Alkynyl Migration to Give Fluorinated Allenyl Complexes of Iridium. Organometallics, 25. 3943-3947 doi:10.1021/om0602916
Hughes, Russell P., King, Mackenzie E., Robinson, David J., Spotts, James M. (1989) Stereoselective oxidative additions of a carbon-carbon .sigma.-bond in tetrafluorocyclopropene to iridium(I) complexes. Journal Of The American Chemical Society, 111 (24) 8919-8920 doi:10.1021/ja00206a025
Bourgeois, Cheryl J., Hughes, Russell P., Yuan, Jian, DiPasquale, Antonio G., Rheingold, Arnold L. (2006) α- and β-Fluorine Elimination Reactions Induced by Reduction of Iridium−Fluoroalkyl Complexes. Selective Formation of Fluoroalkylidene and Hydrofluoroalkene Ligands. Organometallics, 25. 2908-2910 doi:10.1021/om060243l
Hughes, Russell P., Kovacik, Ivan, Lindner, Danielle C., Smith, Jeremy M., Willemsen, Stefan, Zhang, Donghui, Guzei, Ilia A., Rheingold, Arnold L. (2001) Unusual Reactivity of “Proton Sponge” as a Hydride Donor to Transition Metals:  Synthesis and Structural Characterization of Fluoroalkyl(hydrido) Complexes of Iridium(III) and Rhodium(III). Organometallics, 20. 3190-3197 doi:10.1021/om0102347
Yuan, Jian, Hughes, Russell P., Rheingold, Arnold L. (2015) A (pentafluoroethyl)(trifluoromethyl)carbene complex of iridium and reductive activation of its sp3 α, β, and γ carbon–fluorine bonds to give perfluoro-2-butyne, perfluoro-1,2,3-butatriene and perfluoro-1-irida-2-methyl-2-cyclobutene) complexes. Dalton Transactions, 44 (45). 19518-19527 doi:10.1039/c5dt02075a
Garratt, Shaun A., Hughes, Russell P., Kovacik, Ivan, Ward, Antony J., Willemsen, Stefan, Zhang, Donghui (2005) Carbon−Fluorine Bond Activation Coupled with Carbon−Hydrogen Bond Formation α to Iridium:  Kinetics, Mechanism, and Diastereoselectivity. Journal Of The American Chemical Society, 127 (44) 15585-15594 doi:10.1021/ja0545012
Hughes, Russell P. (2009) Conversion of Carbon-Fluorine Bonds α to Transition Metal Centers to Carbon-Hydrogen, Carbon-Carbon, and Carbon-Heteroatom Bonds. European Journal of Inorganic Chemistry, 2009 (31) 4591-4606 doi:10.1002/ejic.200900816
 
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