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Frame, Hannah C., Shen, Longzhu Q., Ryabov, Alexander D., Collins, Terrence J. (2023) On TAML Catalyst Resting State Lifetimes: Kinetic, Mechanistic, and Theoretical Insight into Phosphate-Induced Demetalation of an Iron(III) Bis(sulfonamido)bis(amido)-TAML Catalyst. Inorganic Chemistry, 62 (2) 639-647 doi:10.1021/acs.inorgchem.2c03854

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Reference TypeJournal (article/letter/editorial)
TitleOn TAML Catalyst Resting State Lifetimes: Kinetic, Mechanistic, and Theoretical Insight into Phosphate-Induced Demetalation of an Iron(III) Bis(sulfonamido)bis(amido)-TAML Catalyst
JournalInorganic Chemistry
AuthorsFrame, Hannah C.Author
Shen, Longzhu Q.Author
Ryabov, Alexander D.Author
Collins, Terrence J.Author
Year2023 (January 16)Volume62
Issue2
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/acs.inorgchem.2c03854Search in ResearchGate
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Mindat Ref. ID15672741Long-form Identifiermindat:1:5:15672741:1
GUID0
Full ReferenceFrame, Hannah C., Shen, Longzhu Q., Ryabov, Alexander D., Collins, Terrence J. (2023) On TAML Catalyst Resting State Lifetimes: Kinetic, Mechanistic, and Theoretical Insight into Phosphate-Induced Demetalation of an Iron(III) Bis(sulfonamido)bis(amido)-TAML Catalyst. Inorganic Chemistry, 62 (2) 639-647 doi:10.1021/acs.inorgchem.2c03854
Plain TextFrame, Hannah C., Shen, Longzhu Q., Ryabov, Alexander D., Collins, Terrence J. (2023) On TAML Catalyst Resting State Lifetimes: Kinetic, Mechanistic, and Theoretical Insight into Phosphate-Induced Demetalation of an Iron(III) Bis(sulfonamido)bis(amido)-TAML Catalyst. Inorganic Chemistry, 62 (2) 639-647 doi:10.1021/acs.inorgchem.2c03854
In(2023, January) Inorganic Chemistry Vol. 62 (2) American Chemical Society (ACS)

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Mills, Matthew R., Shen, Longzhu Q., Zhang, David Z., Ryabov, Alexander D., Collins, Terrence J. (2017) Iron(III) Ejection from a “Beheaded” TAML Activator: Catalytically Relevant Mechanistic Insight into the Deceleration of Electrophilic Processes by Electron Donors. Inorganic Chemistry, 56 (17) 10226-10234 doi:10.1021/acs.inorgchem.7b00921
Kundu, Soumen, Shen, Longzhu Q., Somasundar, Yogesh, Annavajhala, Medini, Ryabov, Alexander D., Collins, Terrence J. (2020) TAML- and Buffer-Catalyzed Oxidation of Picric Acid by H2O2: Products, Kinetics, DFT, and the Mechanism of Dual Catalysis. Inorganic Chemistry, 59 (18) 13223-13232 doi:10.1021/acs.inorgchem.0c01581
Shen, Longzhu Q., Kundu, Soumen, Collins, Terrence J., Bominaar, Emile L. (2017) Analysis of Hydrogen Atom Abstraction from Ethylbenzene by an FeVO(TAML) Complex. Inorganic Chemistry, 56 (8) 4347-4356 doi:10.1021/acs.inorgchem.6b02796
Kundu, Soumen, Thompson, Jasper Van Kirk, Shen, Longzhu Q., Mills, Matthew R., Bominaar, Emile L., Ryabov, Alexander D., Collins, Terrence J. (2015) Activation Parameters as Mechanistic Probes in the TAML Iron(V)-Oxo Oxidations of Hydrocarbons. Chemistry - A European Journal, 21 (4). 1803-1810 doi:10.1002/chem.201405024
Mills, Matthew R., Weitz, Andrew C., Zhang, David Z., Hendrich, Michael P., Ryabov, Alexander D., Collins, Terrence J. (2016) A “Beheaded” TAML Activator: A Compromised Catalyst that Emphasizes the Linearity between Catalytic Activity and pKa. Inorganic Chemistry, 55 (23) 12263-12269 doi:10.1021/acs.inorgchem.6b01988
Collins, Terrence J., Ryabov, Alexander D. (2017) Targeting of High-Valent Iron-TAML Activators at Hydrocarbons and Beyond. Chemical Reviews, 117 (13) 9140-9162 doi:10.1021/acs.chemrev.7b00034
Somasundar, Yogesh, Shen, Longzhu Q., Hoane, Alexis G., Tang, Liang L., Mills, Matthew R., Burton, Abigail E., Ryabov, Alexander D., Collins, Terrence J. (2018) Structural, Mechanistic, and Ultradilute Catalysis Portrayal of Substrate Inhibition in the TAML–Hydrogen Peroxide Catalytic Oxidation of the Persistent Drug and Micropollutant, Propranolol. Journal Of The American Chemical Society, 140 (38) 12280-12289 doi:10.1021/jacs.8b08108
Ren, Qizhi, Guo, Yisong, Mills, Matthew R., Ryabov, Alexander D., Collins, Terrence J. (2015) On the Iron(V) Reactivity of an Aggressive Tail-Fluorinated Tetraamido Macrocyclic Ligand (TAML) Activator. European Journal of Inorganic Chemistry, 2015 (8) 1445-1452 doi:10.1002/ejic.201500001
Popescu, Delia-Laura, Vrabel, Melanie, Brausam, Ariane, Madsen, Peter, Lente, Gabor, Fabian, Istvan, Ryabov, Alexander D., van Eldik, Rudi, Collins, Terrence J. (2010) Thermodynamic, Electrochemical, High-Pressure Kinetic, and Mechanistic Studies of the Formation of Oxo FeIV−TAML Species in Water. Inorganic Chemistry, 49 (24) 11439-11448 doi:10.1021/ic1015109
Ghosh, Anindya, Mitchell, Douglas A., Chanda, Arani, Ryabov, Alexander D., Popescu, Delia Laura, Upham, Erin C., Collins, Gregory J., Collins, Terrence J. (2008) Catalase−Peroxidase Activity of Iron(III)−TAML Activators of Hydrogen Peroxide. Journal Of The American Chemical Society, 130 (45) 15116-15126 doi:10.1021/ja8043689
Pal, Parameswar; Anyakora, Chimezie; Ryabov, Alexander D.; Collins, Terrence J. (2025) Catalytic Oxidation of Naphthalene and Polycyclic Arenes by Iron(III) TAML/H2O2 in Water Aiming at Their Efficient Removal from Aqua Natural Systems. Chemistry – A European Journal, 31 (43). doi:10.1002/chem.202500450
 
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