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Kieber-Emmons, Matthew T., Li, Yuqi, Halime, Zakaria, Karlin, Kenneth D., Solomon, Edward I. (2011) Electronic Structure of a Low-Spin Heme/Cu Peroxide Complex: Spin-State and Spin-Topology Contributions to Reactivity. Inorganic Chemistry, 50 (22) 11777-11786 doi:10.1021/ic2018727

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Reference TypeJournal (article/letter/editorial)
TitleElectronic Structure of a Low-Spin Heme/Cu Peroxide Complex: Spin-State and Spin-Topology Contributions to Reactivity
JournalInorganic Chemistry
AuthorsKieber-Emmons, Matthew T.Author
Li, YuqiAuthor
Halime, ZakariaAuthor
Karlin, Kenneth D.Author
Solomon, Edward I.Author
Year2011 (November 21)Volume50
Issue22
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ic2018727Search in ResearchGate
Generate Citation Formats
Mindat Ref. ID1570235Long-form Identifiermindat:1:5:1570235:5
GUID0
Full ReferenceKieber-Emmons, Matthew T., Li, Yuqi, Halime, Zakaria, Karlin, Kenneth D., Solomon, Edward I. (2011) Electronic Structure of a Low-Spin Heme/Cu Peroxide Complex: Spin-State and Spin-Topology Contributions to Reactivity. Inorganic Chemistry, 50 (22) 11777-11786 doi:10.1021/ic2018727
Plain TextKieber-Emmons, Matthew T., Li, Yuqi, Halime, Zakaria, Karlin, Kenneth D., Solomon, Edward I. (2011) Electronic Structure of a Low-Spin Heme/Cu Peroxide Complex: Spin-State and Spin-Topology Contributions to Reactivity. Inorganic Chemistry, 50 (22) 11777-11786 doi:10.1021/ic2018727
In(2011, November) Inorganic Chemistry Vol. 50 (22) American Chemical Society (ACS)

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Halime, Zakaria, Kieber-Emmons, Matthew T., Qayyum, Munzarin F., Mondal, Biplab, Gandhi, Thirumanavelan, Puiu, Simona C., Chufán, Eduardo E., Sarjeant, Amy A. N., Hodgson, Keith O., Hedman, Britt, Solomon, Edward I., Karlin, Kenneth D. (2010) Heme−Copper−Dioxygen Complexes: Toward Understanding Ligand-Environmental Effects on the Coordination Geometry, Electronic Structure, and Reactivity. Inorganic Chemistry, 49 (8) 3629-3645 doi:10.1021/ic9020993
Kieber-Emmons, Matthew T., Qayyum, Munzarin F., Li, Yuqi, Halime, Zakaria, Hodgson, Keith O., Hedman, Britt, Karlin, Kenneth D., Solomon, Edward I. (2012) Spectroscopic Elucidation of a New Heme/Copper Dioxygen Structure Type: Implications for O⋅⋅⋅O Bond Rupture in Cytochrome c Oxidase. Angewandte Chemie, 124 (1). 172-176 doi:10.1002/ange.201104080
Kieber-Emmons, Matthew T., Qayyum, Munzarin F., Li, Yuqi, Halime, Zakaria, Hodgson, Keith O., Hedman, Britt, Karlin, Kenneth D., Solomon, Edward I. (2012) Spectroscopic Elucidation of a New Heme/Copper Dioxygen Structure Type: Implications for O⋅⋅⋅O Bond Rupture in Cytochrome c Oxidase. Angewandte Chemie International Edition, 51 (1). 168-172 doi:10.1002/anie.201104080
Schaefer, Andrew W., Kieber-Emmons, Matthew T., Adam, Suzanne M., Karlin, Kenneth D., Solomon, Edward I. (2017) Phenol-Induced O–O Bond Cleavage in a Low-Spin Heme–Peroxo–Copper Complex: Implications for O2 Reduction in Heme–Copper Oxidases. Journal Of The American Chemical Society, 139 (23) 7958-7973 doi:10.1021/jacs.7b03292
Kim, Hyun, Sharma, Savita K., Schaefer, Andrew W., Solomon, Edward I., Karlin, Kenneth D. (2019) Heme–Cu Binucleating Ligand Supports Heme/O2 and FeII–CuI/O2 Reactivity Providing High- and Low-Spin FeIII–Peroxo–CuII Complexes. Inorganic Chemistry, 58 (22) 15423-15432 doi:10.1021/acs.inorgchem.9b02521
Cao, Rui, Saracini, Claudio, Ginsbach, Jake W., Kieber-Emmons, Matthew T., Siegler, Maxime A., Solomon, Edward I., Fukuzumi, Shunichi, Karlin, Kenneth D. (2016) Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy. Journal Of The American Chemical Society, 138 (22) 7055-7066 doi:10.1021/jacs.6b02404
Lehnert, Nicolai, Fujisawa, Kiyoshi, Solomon, Edward I. (2003) Electronic Structure and Reactivity of High-Spin Iron−Alkyl- and −Pterinperoxo Complexes. Inorganic Chemistry, 42 (2) 469-481 doi:10.1021/ic020496g
Lee, Yunho, Lee, Dong-Heon, Park, Ga Young, Lucas, Heather R., Narducci Sarjeant, Amy A., Kieber-Emmons, Matthew T., Vance, Michael A., Milligan, Ashley E., Solomon, Edward I., Karlin, Kenneth D. (2010) Sulfur Donor Atom Effects on Copper(I)/O2Chemistry with Thioanisole Containing Tetradentate N3S Ligand Leading to μ-1,2-Peroxo-Dicopper(II) Species. Inorganic Chemistry, 49 (19) 8873-8885 doi:10.1021/ic101041m
Kieber-Emmons, Matthew T., Ginsbach, Jake W., Wick, Patrick K., Lucas, Heather R., Helton, Matthew E., Lucchese, Baldo, Suzuki, Masatatsu, Zuberbühler, Andreas D., Karlin, Kenneth D., Solomon, Edward I. (2014) Observation of a CuII2(μ-1,2-peroxo)/CuIII2(μ-oxo)2Equilibrium and its Implications for Copper-Dioxygen Reactivity. Angewandte Chemie, 126 (19). 5035-5039 doi:10.1002/ange.201402166
Kieber-Emmons, Matthew T., Ginsbach, Jake W., Wick, Patrick K., Lucas, Heather R., Helton, Matthew E., Lucchese, Baldo, Suzuki, Masatatsu, Zuberbühler, Andreas D., Karlin, Kenneth D., Solomon, Edward I. (2014) Observation of a CuII2(μ-1,2-peroxo)/CuIII2(μ-oxo)2Equilibrium and its Implications for Copper-Dioxygen Reactivity. Angewandte Chemie International Edition, 53 (19). 4935-4939 doi:10.1002/anie.201402166
Garcia-Bosch, Isaac, Adam, Suzanne M., Schaefer, Andrew W., Sharma, Savita K., Peterson, Ryan L., Solomon, Edward I., Karlin, Kenneth D. (2015) A “Naked” FeIII-(O22–)-CuII Species Allows for Structural and Spectroscopic Tuning of Low-Spin Heme-Peroxo-Cu Complexes. Journal Of The American Chemical Society, 137 (3) 1032-1035 doi:10.1021/ja5115198
 
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