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Mednikov, Evgueni G., Ivanov, Sergei A., Dahl, Lawrence F. (2011) CO-Induced Formation of an Interpenetrating Bicuboctahedral Au2Pd18Kernel in Nanosized Au2Pd28(CO)26(PEt3)10: Formal Replacement of an Interior (μ12-Pd)2Fragment in the Corresponding Known Isostructural Homopalladium Pd30(CO)26(PEt3)10with Nonisovalent (μ12-Au)2and Resulting Experimental/Theoretical Implications. Inorganic Chemistry, 50 (22) 11795-11806 doi:10.1021/ic201923y

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Reference TypeJournal (article/letter/editorial)
TitleCO-Induced Formation of an Interpenetrating Bicuboctahedral Au2Pd18Kernel in Nanosized Au2Pd28(CO)26(PEt3)10: Formal Replacement of an Interior (μ12-Pd)2Fragment in the Corresponding Known Isostructural Homopalladium Pd30(CO)26(PEt3)10with Nonisovalent (μ12-Au)2and Resulting Experimental/Theoretical Implications
JournalInorganic Chemistry
AuthorsMednikov, Evgueni G.Author
Ivanov, Sergei A.Author
Dahl, Lawrence F.Author
Year2011 (November 21)Volume50
Issue22
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ic201923ySearch in ResearchGate
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Mindat Ref. ID1570260Long-form Identifiermindat:1:5:1570260:1
GUID0
Full ReferenceMednikov, Evgueni G., Ivanov, Sergei A., Dahl, Lawrence F. (2011) CO-Induced Formation of an Interpenetrating Bicuboctahedral Au2Pd18Kernel in Nanosized Au2Pd28(CO)26(PEt3)10: Formal Replacement of an Interior (μ12-Pd)2Fragment in the Corresponding Known Isostructural Homopalladium Pd30(CO)26(PEt3)10with Nonisovalent (μ12-Au)2and Resulting Experimental/Theoretical Implications. Inorganic Chemistry, 50 (22) 11795-11806 doi:10.1021/ic201923y
Plain TextMednikov, Evgueni G., Ivanov, Sergei A., Dahl, Lawrence F. (2011) CO-Induced Formation of an Interpenetrating Bicuboctahedral Au2Pd18Kernel in Nanosized Au2Pd28(CO)26(PEt3)10: Formal Replacement of an Interior (μ12-Pd)2Fragment in the Corresponding Known Isostructural Homopalladium Pd30(CO)26(PEt3)10with Nonisovalent (μ12-Au)2and Resulting Experimental/Theoretical Implications. Inorganic Chemistry, 50 (22) 11795-11806 doi:10.1021/ic201923y
In(2011, November) Inorganic Chemistry Vol. 50 (22) American Chemical Society (ACS)

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Mednikov, Evgueni G., Dahl, Lawrence F. (2015) Acid/Base-Controlled AuI/Au0Reductive Transformations of the Monogold [(μ14-Au)Pd22(CO)20(PEt3)8]+Monocation into Three Different Neutral Digold Nanoclusters: Au2Pd21(CO)20(PEt3)10, Au2Pd28(CO)26(PEt3)10, and New Five-Layer Hexagonal Close-Packed (μ12-Au)2Pd42(CO)30(PEt3)12with a Trigonal-Bipyramidal AuPd3Au Kernel. Inorganic Chemistry, 54 (3) 1145-1151 doi:10.1021/ic502470m
Mednikov, Eugeny G., Ivanov, Sergei A., Dahl, Lawrence F. (2003) [Pd30(CO)26(PEt3)10] and [Pd54(CO)40(PEt3)14]: Generation of Nanosized Pd30- and Pd54-Core Geometries Containing Interpenetrating Cuboctahedral-Based Metal Polyhedra. Angewandte Chemie International Edition, 42 (3). 323-327 doi:10.1002/anie.200390107
Mednikov, Evgueni G., Ivanov, Sergei A., Slovokhotova, Irina V., Dahl, Lawrence F. (2005) Nanosized [Pd52(CO)36(PEt3)14] and [Pd66(CO)45(PEt3)16] Clusters Based on a Hypothetical Pd38 Vertex-Truncatedν3 Octahedron. Angewandte Chemie, 117 (42). 7008-7014 doi:10.1002/ange.200502307
Mednikov, Evgueni G., Ivanov, Sergei A., Slovokhotova, Irina V., Dahl, Lawrence F. (2005) Nanosized [Pd52(CO)36(PEt3)14] and [Pd66(CO)45(PEt3)16] Clusters Based on a Hypothetical Pd38 Vertex-Truncatedν3 Octahedron. Angewandte Chemie International Edition, 44 (42). 6848-6854 doi:10.1002/anie.200502307
Mednikov, Evgueni G., Ivanov, Sergei A., Dahl, Lawrence F. (2015) Nanosized {Pd4(μ4-C)}Pd32(CO)28(PMe3)14Containing Tetrahedrally Deformed Pd4Cage with Encapsulated Carbide Atom: Formal Substitution of Geometrically Analogous Interior Au4Entity in Isostructural Au4Pd32(CO)28(PMe3)14by Electronically Equivalent Pd4(μ4-C) and Computational/Catalytic Implications. Inorganic Chemistry, 54 (13) 6157-6168 doi:10.1021/acs.inorgchem.5b00208
Ivanov, Sergei A., Mednikov, Evgueni G., Dahl, Lawrence F. (2023) Octahedral Hexapalladium Pseudo-Td Pd6(μ3-CO)4(PEt3)6 with 80 Electron-Deficient Cluster Valence Electrons (CVEs) and a Comparison with Octahedral Hexapalladium Pseudo-C2v Pd6(μ3-CO)4(PMe3)7 with 82 CVEs: Computational Analysis and Resulting Implications. Inorganic Chemistry, 62 (1) 18-24 doi:10.1021/acs.inorgchem.2c03542
Mednikov, Evgueni G., Jewell, Matthew C., Dahl, Lawrence F. (2007) Nanosized (μ12-Pt)Pd164-xPtx(CO)72(PPh3)20(x≈ 7) Containing Pt-Centered Four-Shell 165-Atom Pd−Pt Core with Unprecedented Intershell Bridging Carbonyl Ligands:  Comparative Analysis of Icosahedral Shell-Growth Patterns with Geometrically Related Pd145(CO)x(PEt3)30(x≈ 60) Containing Capped Three-Shell Pd145Core. Journal Of The American Chemical Society, 129 (37) 11619-11630 doi:10.1021/ja073945q
Mednikov, Evgueni G., Dahl, Lawrence F. (2008) Nanosized Pd37(CO)28{P(p-Tolyl)3}12Containing Geometrically Unprecedented Central 23-Atom Interpenetrating Tri-icosahedral Palladium Kernel of Double Icosahedral Units: Its Postulated Metal-Core Evolution and Resulting Stereochemical Implications. Journal Of The American Chemical Society, 130 (44) 14813-14821 doi:10.1021/ja805679j
Mednikov, Evgueni G., Dahl, Lawrence F. (2013) Ion Exchange of Protons by Coinage Metals to Give Gold and Silver Encapsulation within a Pseudo-D2dDistorted Face-Capped Pd14Cubic Kernel: [(μ14-M)Pd22(CO)20(PEt3)8]+(M=Au, Ag). Angewandte Chemie, 125 (30). 7967-7971 doi:10.1002/ange.201301982
Mednikov, Evgueni G., Dahl, Lawrence F. (2013) Ion Exchange of Protons by Coinage Metals to Give Gold and Silver Encapsulation within a Pseudo-D2dDistorted Face-Capped Pd14Cubic Kernel: [(μ14-M)Pd22(CO)20(PEt3)8]+(M=Au, Ag). Angewandte Chemie International Edition, 52 (30). 7813-7817 doi:10.1002/anie.201301982
Mednikov, Evgueni G., Dahl, Lawrence F. (2005) First high-nuclearity palladium halide/carbonyl/phosphine cluster, [Pd12(μ3-I)2(μ4-I)3(μ2-CO)6(PEt3)6]+ monocation containing an octacapped octahedral Pd6(μ3-Pd)6(μ3-I)2 fragment: structure-to-synthesis generation from different synthetic routes. Inorganica Chimica Acta, 358 (5). 1557-1570 doi:10.1016/j.ica.2004.09.064
 
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