Vote for your favorite mineral in #MinCup25! - Kosmochlor vs. Azurite
It's a battle of green vs blue as rare but vibrant chromium-bearing kosmochlor up against the deep blue copper alteration mineral azurite.
Log InRegister
Quick Links : The Mindat ManualThe Rock H. Currier Digital LibraryMindat Newsletter [Free Download]
Home PageAbout MindatThe Mindat ManualHistory of MindatCopyright StatusWho We AreContact UsAdvertise on Mindat
Donate to MindatCorporate SponsorshipSponsor a PageSponsored PagesMindat AdvertisersAdvertise on Mindat
Learning CenterWhat is a mineral?The most common minerals on earthInformation for EducatorsMindat ArticlesThe ElementsThe Rock H. Currier Digital LibraryGeologic Time
Minerals by PropertiesMinerals by ChemistryAdvanced Locality SearchRandom MineralRandom LocalitySearch by minIDLocalities Near MeSearch ArticlesSearch GlossaryMore Search Options
Search For:
Mineral Name:
Locality Name:
Keyword(s):
 
The Mindat ManualAdd a New PhotoRate PhotosLocality Edit ReportCoordinate Completion ReportAdd Glossary Item
Mining CompaniesStatisticsUsersMineral MuseumsClubs & OrganizationsMineral Shows & EventsThe Mindat DirectoryDevice SettingsThe Mineral Quiz
Photo SearchPhoto GalleriesSearch by ColorNew Photos TodayNew Photos YesterdayMembers' Photo GalleriesPast Photo of the Day GalleryPhotography

Rankin, Matthew A., MacLean, Darren F., Schatte, Gabriele, McDonald, Robert, Stradiotto, Mark (2007) Silylene Extrusion from Organosilanes via Double Geminal Si−H Bond Activation by a Cp*Ru(κ2-P,N)+Complex:  Observation of a Key Stoichiometric Step in the Glaser−Tilley Alkene Hydrosilylation Mechanism. Journal Of The American Chemical Society, 129 (51) 15855-15864 doi:10.1021/ja0768800

Advanced
   -   Only viewable:
Reference TypeJournal (article/letter/editorial)
TitleSilylene Extrusion from Organosilanes via Double Geminal Si−H Bond Activation by a Cp*Ru(κ2-P,N)+Complex:  Observation of a Key Stoichiometric Step in the Glaser−Tilley Alkene Hydrosilylation Mechanism
JournalJournal Of The American Chemical Society
AuthorsRankin, Matthew A.Author
MacLean, Darren F.Author
Schatte, GabrieleAuthor
McDonald, RobertAuthor
Stradiotto, MarkAuthor
Year2007 (December)Volume129
Issue51
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja0768800Search in ResearchGate
Generate Citation Formats
Mindat Ref. ID1692076Long-form Identifiermindat:1:5:1692076:3
GUID0
Full ReferenceRankin, Matthew A., MacLean, Darren F., Schatte, Gabriele, McDonald, Robert, Stradiotto, Mark (2007) Silylene Extrusion from Organosilanes via Double Geminal Si−H Bond Activation by a Cp*Ru(κ2-P,N)+Complex:  Observation of a Key Stoichiometric Step in the Glaser−Tilley Alkene Hydrosilylation Mechanism. Journal Of The American Chemical Society, 129 (51) 15855-15864 doi:10.1021/ja0768800
Plain TextRankin, Matthew A., MacLean, Darren F., Schatte, Gabriele, McDonald, Robert, Stradiotto, Mark (2007) Silylene Extrusion from Organosilanes via Double Geminal Si−H Bond Activation by a Cp*Ru(κ2-P,N)+Complex:  Observation of a Key Stoichiometric Step in the Glaser−Tilley Alkene Hydrosilylation Mechanism. Journal Of The American Chemical Society, 129 (51) 15855-15864 doi:10.1021/ja0768800
In(2007, December) Journal Of The American Chemical Society Vol. 129 (51) American Chemical Society (ACS)

See Also

These are possibly similar items as determined by title/reference text matching only.

Rankin, Matthew A., Schatte, Gabriele, McDonald, Robert, Stradiotto, Mark (2007) Remarkably Facile and Reversible Ru−C(sp3) Bond Cleavage to Give a Reactive 16-Electron Cp*Ru(κ2-P,Carbene) Zwitterion. Journal Of The American Chemical Society, 129 (20) 6390-6391 doi:10.1021/ja071684e
Rankin, Matthew A., MacLean, Darren F., McDonald, Robert, Ferguson, Michael J., Lumsden, Michael D., Stradiotto, Mark (2009) Probing the Dynamics and Reactivity of a Stereochemically Nonrigid Cp*Ru(H)(κ2-P,Carbene) Complex. Organometallics, 28. 74-83 doi:10.1021/om800761c
Rankin, Matthew A., Schatte, Gabriele, McDonald, Robert, Stradiotto, Mark (2008) Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage. Organometallics, 27. 6286-6299 doi:10.1021/om800740z
Rankin, Matthew A., McDonald, Robert, Ferguson, Michael J., Stradiotto, Mark (2005) Coordinatively Unsaturated Cationic and Zwitterionic [Cp*Ru(κ2-P,N)] Complexes: Ligand-Assisted Double-Geminal CH Bond Activation and Reversible α-H Elimination at Ruthenium. Angewandte Chemie, 117 (23). 3669-3672 doi:10.1002/ange.200500528
Rankin, Matthew A., McDonald, Robert, Ferguson, Michael J., Stradiotto, Mark (2005) Coordinatively Unsaturated Cationic and Zwitterionic [Cp*Ru(κ2-P,N)] Complexes: Ligand-Assisted Double-Geminal CH Bond Activation and Reversible α-H Elimination at Ruthenium. Angewandte Chemie International Edition, 44 (23). 3603-3606 doi:10.1002/anie.200500528
Rankin, Matthew A., McDonald, Robert, Ferguson, Michael J., Stradiotto, Mark (2005) Exploring the Influence of Ancillary Ligand Charge and Geometry on the Properties of New Coordinatively Unsaturated Cp*(κ2-P,N)Ru+Complexes:  Linkage Isomerism, Double C−H Bond Activation, and Reversible α-Hydride Elimination. Organometallics, 24. 4981-4994 doi:10.1021/om050534e
Hesp, Kevin D., Wechsler, Dominik, Cipot, Judy, Myers, Anne, McDonald, Robert, Ferguson, Michael J., Schatte, Gabriele, Stradiotto, Mark (2007) Exploring the Utility of Neutral Rhodium and Iridium κ2-P,Oand κ2-P(S),OComplexes as Catalysts for Alkene Hydrogenation and Hydrosilylation. Organometallics, 26. 5430-5437 doi:10.1021/om7006437
Wechsler, Dominik, Rankin, Matthew A., McDonald, Robert, Ferguson, Michael J., Schatte, Gabriele, Stradiotto, Mark (2007) New Racemic Planar-Chiral Metalloligands Derived from Donor-Substituted Indenes:  A Synthetic, Structural, and Catalytic Investigation. Organometallics, 26. 6418-6427 doi:10.1021/om700832f
Glaser, Paul B., Tilley, T. Don (2003) Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism. Journal Of The American Chemical Society, 125 (45) 13640-13641 doi:10.1021/ja037620v
Lundgren, Rylan J., Rankin, Matthew A., McDonald, Robert, Schatte, Gabriele, Stradiotto, Mark (2007) A Formally Zwitterionic Ruthenium Catalyst Precursor for the Transfer Hydrogenation of Ketones that Does Not Feature an Ancillary Ligand NH Functionality. Angewandte Chemie, 119 (25). 4816-4819 doi:10.1002/ange.200700345
Morgan, Erin, MacLean, Darren F., McDonald, Robert, Turculet, Laura (2009) Rhodium and Iridium Amido Complexes Supported by Silyl Pincer Ligation: Ammonia N−H Bond Activation by a [PSiP]Ir Complex. Journal Of The American Chemical Society, 131 (40) 14234-14236 doi:10.1021/ja906646v
 
and/or  
Mindat.org is an outreach project of the Hudson Institute of Mineralogy, a 501(c)(3) not-for-profit organization.
Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2025, except where stated. Most political location boundaries are © OpenStreetMap contributors. Mindat.org relies on the contributions of thousands of members and supporters. Founded in 2000 by Jolyon Ralph.
To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
Privacy Policy - Terms & Conditions - Contact Us / DMCA issues - Report a bug/vulnerability Current server date and time: September 9, 2025 07:33:03
Go to top of page