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Larsen, R. B., Jacamon, F., Kronz, A. (2009) Trace element chemistry and textures of quartz during the magmatic hydrothermal transition of Oslo Rift granites. Mineralogical Magazine, 73 (4) 691-707 doi:10.1180/minmag.2009.073.4.691

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Reference TypeJournal (article/letter/editorial)
TitleTrace element chemistry and textures of quartz during the magmatic hydrothermal transition of Oslo Rift granites
JournalMineralogical Magazine
AuthorsLarsen, R. B.Author
Jacamon, F.Author
Kronz, A.Author
Year2009 (August)Volume73
Issue4
PublisherMineralogical Society
URL
DOIdoi:10.1180/minmag.2009.073.4.691Search in ResearchGate
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Mindat Ref. ID16990412Long-form Identifiermindat:1:5:16990412:0
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Full ReferenceLarsen, R. B., Jacamon, F., Kronz, A. (2009) Trace element chemistry and textures of quartz during the magmatic hydrothermal transition of Oslo Rift granites. Mineralogical Magazine, 73 (4) 691-707 doi:10.1180/minmag.2009.073.4.691
Plain TextLarsen, R. B., Jacamon, F., Kronz, A. (2009) Trace element chemistry and textures of quartz during the magmatic hydrothermal transition of Oslo Rift granites. Mineralogical Magazine, 73 (4) 691-707 doi:10.1180/minmag.2009.073.4.691
In(2009, August) Mineralogical Magazine Vol. 73 (4) Mineralogical Society
Abstract/Notes This study documents the textures and chemical evolution of igneous quartz
(Qz) in granite from the Oslo Rift (Norway) during the magmatic-hydrothermal
transition. Contrary to the other major igneous phases, primary quartz is well
preserved. SEM-CL imaging documents four types of quartz (Qz1— Qz4). Qz1: bright
primary magmatic quartz that grew under H2O-undersaturated
conditions and developed a conspicuous sector zoning. Qz2: light grey luminescent
secondary quartz that surrounds Qz1 and altered Qz1 in a ‘non-destructive’
process. Qz3: is usually darker than Qz2 and intersects Qz1 and Qz2. It is formed
by dissolution/recrystallization processes involving saline deuteric fluids. Qz4:
found in narrow cracks and patches of black quartz intersecting all the other
types. EPMA in situ analyses of the different quartz
generations confirm that the intensity of luminescence of quartz is positively
correlated with the Ti content of the quartz. Aluminium and K are mostly
incorporated in quartz in the form of
[AlO4/K+]0
centre defects. In the Drammen granite, the Ti and Al contents of Qz1 averages 200
ppm and 80 ppm respectively. Titanium in Qz1 varies from 50 to 95 ppm in the
peralkaline granite known as ekerite, whereas Al is irregular and ranges between
100 ppm and values below the limit of detection (LODAl at 2σ
= 14 ppm). In all samples, Qz2 and Qz3 are strongly depleted in Ti and Al compared
to Qz1. Either the Ti content in Qz2 is falling gradually towards Qz1 or more
abruptly, whereas it is sharp from Qz3 towards Qz1 and Qz2. Potassium is variable
in all four quartz types and samples, and ranges from values below the detection
limit (LODk, at 2σ = 8 ppm) to 120 ppm. Grains in Qz4, being
only 1–2µm wide, could not be resolved with the EPMA beam. In all granites, quartz
crystallized from haplogranitic melts at P ~1.5 kbar
and T = 700—750°C. SEM-CL and EPMA studies of igneous
Oslo Rift quartz illustrate vividly the complex chemical and physical processes
that characterize the magmatic-hydrothermal transition in shallow granitic systems
and show that the chemistry of primary aqueous fluids is strongly modified from
its primary igneous composition before eventually being expelled from the granitic
system and perhaps incorporated in ore-forming hydrothermal convection
systems.


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