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Ortega, L., Vindel, E., Beny, C. (1991) C-O-H-N fluid inclusions associated with gold-stibnite mineralization in low-grade metamorphic rocks, Mari Rosa mine, Caceres, Spain. Mineralogical Magazine, 55 (379) 235-247 doi:10.1180/minmag.1991.055.379.12

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Reference TypeJournal (article/letter/editorial)
TitleC-O-H-N fluid inclusions associated with gold-stibnite mineralization in low-grade metamorphic rocks, Mari Rosa mine, Caceres, Spain
JournalMineralogical MagazineISSN0026-461X
AuthorsOrtega, L.Author
Vindel, E.Author
Beny, C.Author
Year1991 (June)Volume55
Issue379
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_55/55-379-235.pdf+
DOIdoi:10.1180/minmag.1991.055.379.12Search in ResearchGate
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Mindat Ref. ID1720Long-form Identifiermindat:1:5:1720:0
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Full ReferenceOrtega, L., Vindel, E., Beny, C. (1991) C-O-H-N fluid inclusions associated with gold-stibnite mineralization in low-grade metamorphic rocks, Mari Rosa mine, Caceres, Spain. Mineralogical Magazine, 55 (379) 235-247 doi:10.1180/minmag.1991.055.379.12
Plain TextOrtega, L., Vindel, E., Beny, C. (1991) C-O-H-N fluid inclusions associated with gold-stibnite mineralization in low-grade metamorphic rocks, Mari Rosa mine, Caceres, Spain. Mineralogical Magazine, 55 (379) 235-247 doi:10.1180/minmag.1991.055.379.12
In(1991, June) Mineralogical Magazine Vol. 55 (379) Mineralogical Society
Abstract/NotesAbstractThe Mari Rosa mine lies within a low-grade Precambrian alternating series of black shales and metagreywackes in the Spanish Hercynian massif. There are two generations of mineralized veins: V2, gold-(stibnite)-bearing quartz veins, parallel to the main cleavage, and V3, stibnite-bearing quartz veins which postdate the main deformation event.Four main types of inclusions have been identified. Type I, II and IV are aqueous-carbonaceous inclusions, with variable degrees of filling, while type III are non-aqueous and typically single-phase at room temperature. Except for type I (absent in V3), similar inclusions have been observed in both V2 and V3 veins. Gas compositions are always characterised by CH4-N2-CO2 assemblages, ranging from CO2-rich mixtures in the earliest inclusions (type I), to N2-rich mixtures in the latest inclusions (type IV).Gold precipitation in V2 veins can be related to type I inclusions at T > 380°C (TH = 300–380°C). A subsequent drop in XCO2 and cooling are recorded in type II and III inclusions, interpreted to be the result of unmixing of a previously homogeneous fluid derived from type I. This boiling would provoke the precipitation of stibnite at 300°C and 1 kbar. The type IV inclusions, which are the richest in H2O, represent a late fluid circulation at lower temperatures (TH = 190–280°C).


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