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Satpathy, Jagnyesh K., Yadav, Rolly, Bagha, Umesh K., Kumar, Devesh, Sastri, Chivukula V., de Visser, Sam P. (2024) Enhanced Reactivity through Equatorial Sulfur Coordination in Nonheme Iron(IV)–Oxo Complexes: Insights from Experiment and Theory. Inorganic Chemistry, 63 (15) 6752-6766 doi:10.1021/acs.inorgchem.4c00070

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Reference TypeJournal (article/letter/editorial)
TitleEnhanced Reactivity through Equatorial Sulfur Coordination in Nonheme Iron(IV)–Oxo Complexes: Insights from Experiment and Theory
JournalInorganic Chemistry
AuthorsSatpathy, Jagnyesh K.Author
Yadav, RollyAuthor
Bagha, Umesh K.Author
Kumar, DeveshAuthor
Sastri, Chivukula V.Author
de Visser, Sam P.Author
Year2024 (April 15)Volume63
Issue15
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/acs.inorgchem.4c00070Search in ResearchGate
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Mindat Ref. ID17305087Long-form Identifiermindat:1:5:17305087:5
GUID0
Full ReferenceSatpathy, Jagnyesh K., Yadav, Rolly, Bagha, Umesh K., Kumar, Devesh, Sastri, Chivukula V., de Visser, Sam P. (2024) Enhanced Reactivity through Equatorial Sulfur Coordination in Nonheme Iron(IV)–Oxo Complexes: Insights from Experiment and Theory. Inorganic Chemistry, 63 (15) 6752-6766 doi:10.1021/acs.inorgchem.4c00070
Plain TextSatpathy, Jagnyesh K., Yadav, Rolly, Bagha, Umesh K., Kumar, Devesh, Sastri, Chivukula V., de Visser, Sam P. (2024) Enhanced Reactivity through Equatorial Sulfur Coordination in Nonheme Iron(IV)–Oxo Complexes: Insights from Experiment and Theory. Inorganic Chemistry, 63 (15) 6752-6766 doi:10.1021/acs.inorgchem.4c00070
In(2024, April) Inorganic Chemistry Vol. 63 (15) American Chemical Society (ACS)

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Bagha, Umesh Kumar, Yadav, Rolly, Mokkawes, Thirakorn, Satpathy, Jagnyesh Kumar, Kumar, Devesh, Sastri, Chivukula V., de Visser, Sam P. (2023) Defluorination of Fluorophenols by a Nonheme Iron(IV)‐Oxo Species: Observation of a New Intermediate Along the Reaction. Chemistry – A European Journal, 29 (39) doi:10.1002/chem.202300478
Sahoo, Limashree, Satpathy, Jagnyesh Kumar, Yadav, Rolly, de Visser, Sam P., Sastri, Chivukula V. (2023) Equatorial Perturbation Driven Reaction Bifurcation in Non‐Heme Iron Complexes for Chlorite Oxidation. European Journal of Inorganic Chemistry, 26 (33) doi:10.1002/ejic.202300380
Mukherjee, Gourab, Reinhard, Fabián G. Cantú, Bagha, Umesh Kumar, Sastri, Chivukula V., de Visser, Sam P. (2020) Sluggish reactivity by a nonheme iron(iv)-tosylimido complex as compared to its oxo analogue. Dalton Transactions, 49 (18) 5921-5931 doi:10.1039/d0dt00018c
Vardhaman, Anil Kumar, Barman, Prasenjit, Kumar, Suresh, Sastri, Chivukula V., Kumar, Devesh, de Visser, Sam P. (2013) Comparison of the Reactivity of Nonheme Iron(IV)-Oxo versus Iron(IV)-Imido Complexes: Which is the Better Oxidant?. Angewandte Chemie, 125 (47). 12514-12518 doi:10.1002/ange.201305370
Vardhaman, Anil Kumar, Barman, Prasenjit, Kumar, Suresh, Sastri, Chivukula V., Kumar, Devesh, de Visser, Sam P. (2013) Comparison of the Reactivity of Nonheme Iron(IV)-Oxo versus Iron(IV)-Imido Complexes: Which is the Better Oxidant?. Angewandte Chemie International Edition, 52 (47). 12288-12292 doi:10.1002/anie.201305370
Hermano Sampaio Dias, Artur, Yadav, Rolly, Mokkawes, Thirakorn, Kumar, Asheesh, Skaf, Munir S., Sastri, Chivukula V., Kumar, Devesh, de Visser, Sam P. (2023) Biotransformation of Bisphenol by Human Cytochrome P450 2C9 Enzymes: A Density Functional Theory Study. Inorganic Chemistry, 62 (5) 2244-2256 doi:10.1021/acs.inorgchem.2c03984
Barman, Prasenjit, Cantú Reinhard, Fabián G., Bagha, Umesh Kumar, Kumar, Devesh, Sastri, Chivukula V., de Visser, Sam P. (2019) Hydrogen by Deuterium Substitution in an Aldehyde Tunes the Regioselectivity by a Nonheme Manganese(III)–Peroxo Complex. Angewandte Chemie, 131 (31). 10749-10753 doi:10.1002/ange.201905416
Barman, Prasenjit, Cantú Reinhard, Fabián G., Bagha, Umesh Kumar, Kumar, Devesh, Sastri, Chivukula V., de Visser, Sam P. (2019) Hydrogen by Deuterium Substitution in an Aldehyde Tunes the Regioselectivity by a Nonheme Manganese(III)–Peroxo Complex. Angewandte Chemie International Edition, 58 (31). 10639-10643 doi:10.1002/anie.201905416
Kalita, Nitul, Satpathy, Jagnyesh K., Yadav, Rolly, Sastri, Chivukula V., Qureshi, Mohammad (2025) Integrating Homogeneous and Heterogeneous Catalytic Systems for Synergistic Water Oxidation: Role of Geometrically Distinct Bispidine Metal Complexes. Chemistry of Materials, 37 (5). doi:10.1021/acs.chemmater.5c00049
Kumar, Suresh, Faponle, Abayomi S., Barman, Prasenjit, Vardhaman, Anil Kumar, Sastri, Chivukula V., Kumar, Devesh, de Visser, Sam P. (2014) Long-Range Electron Transfer Triggers Mechanistic Differences between Iron(IV)-Oxo and Iron(IV)-Imido Oxidants. Journal Of The American Chemical Society, 136 (49) 17102-17115 doi:10.1021/ja508403w
Vardhaman, Anil Kumar, Sastri, Chivukula V., Kumar, Devesh, de Visser, Sam P. (2011) Nonheme ferric hydroperoxo intermediates are efficient oxidants of bromide oxidation. Chemical Communications, 47 (39). 11044pp. doi:10.1039/c1cc13775a
 
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