Reference Type | Journal (article/letter/editorial) |
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Title | Micron-to-nanoscale investigation of Cu-Fe-Ni sulfide inclusions within laurite (Ru, Os)S2 from chromitites |
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Journal | Mineralium Deposita |
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Authors | González-Jiménez, José María | Author |
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González-Pérez, Igor | Author |
Plissart, Gaëlle | Author |
Ferreira, Amira R. | Author |
Schettino, Erwin | Author |
Yesares, Lola | Author |
Schilling, Manuel E. | Author |
Corgne, Alexandre | Author |
Gervilla, Fernando | Author |
Year | 2025 (March) | Volume | 60 |
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Page(s) | 581-604 | Issue | 2 |
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Publisher | Springer Science and Business Media LLC |
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DOI | doi:10.1007/s00126-024-01285-0Search in ResearchGate |
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Classification | Not set | LoC | Not set |
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Mindat Ref. ID | 18032206 | Long-form Identifier | mindat:1:5:18032206:4 |
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GUID | 0 |
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Full Reference | González-Jiménez, José María; González-Pérez, Igor; Plissart, Gaëlle; Ferreira, Amira R.; Schettino, Erwin; Yesares, Lola; Schilling, Manuel E.; Corgne, Alexandre; Gervilla, Fernando (2025) Micron-to-nanoscale investigation of Cu-Fe-Ni sulfide inclusions within laurite (Ru, Os)S2 from chromitites. Mineralium Deposita, 60 (2). 581-604 doi:10.1007/s00126-024-01285-0 |
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Plain Text | González-Jiménez, José María; González-Pérez, Igor; Plissart, Gaëlle; Ferreira, Amira R.; Schettino, Erwin; Yesares, Lola; Schilling, Manuel E.; Corgne, Alexandre; Gervilla, Fernando (2025) Micron-to-nanoscale investigation of Cu-Fe-Ni sulfide inclusions within laurite (Ru, Os)S2 from chromitites. Mineralium Deposita, 60 (2). 581-604 doi:10.1007/s00126-024-01285-0 |
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In | (2025, March) Mineralium Deposita Vol. 60 (2). Springer Science and Business Media LLC |
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Abstract/Notes | This paper provides a top-down nanoscale analysis of Cu-Ni-Fe sulfide inclusions in laurite from the Taitao ophiolite (Chile) and the Kevitsa mafic-ultramafic igneous intrusion (Finland). High-resolution transmission electron microscopy (HRTEM) reveal that Cu-Ni-Fe sulfide inclusions are euhedral to (sub)-anhedral (i.e., droplet-like) and form single, biphasic or polyphasic grains, made up of different polymorphs, polytypes and polysomes even within a single sulfide crystal. Tetragonal (I4− 2 d) and cubic (F− 4 3m) chalcopyrite (CuFeS2) host frequent fringes of bornite (Cu5FeS4; cubic F− 4 3m and/ or orthorhombic Pbca)±talnakhite (Cu9(Fe, Ni)8S16; cubic I− 4 3m)±pyrrhotite (Fe1−xS; monoclinic C2/c polytype 4C and orthorhombic Cmca polytype 11C)±pentlandite ((Ni, Fe)9S8; cubic Fm3m). Pentlandite hosts fringes of pyrrhotite, bornite and/or talnakhite. Laurite and Cu-Fe-Ni sulfide inclusions display coherent, semi-coherent and incoherent crystallographic orientation relationships (COR), defined by perfect edge-to-edge matching, as well as slight (2–4º) to significant (45º) lattice misfit. These COR suggest diverse mechanisms of crystal growth of Cu-Fe-Ni sulfide melt mechanically trapped by growing laurite. Meanwhile, the mutual COR within the sulfide inclusions discloses: (1) Fe-Ni-S melt solidified into MSS re-equilibrated after cooling into pyrrhotite±pentlandite, (2) Cu-Ni-Fe-S melts crystallized into the quaternary solid solution spanning the compositional range between heazlewoodite [(Ni, Fe)3±xS2] (Hzss) and ISS [(Cu1±x, Fe1±y)S2]. Additionally, nanocrystallites (50–100 nm) of Pt-S and iridarsenite (IrAsS) accompanying the sulfide inclusions spotlight the segregation of PGE-rich sulfide and arsenide melt earlier and/or contemporarily to laurite crystallization from the silicate magmas. Cobaltite (CoAsS)-gersdorffite (NiAsS) epitaxially overgrown on laurite further supports the segregation of arsenide melts at early stages of chromitite formation. |
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| Not Yet Imported: Journal of Materials Science & Technology - journal-article : 10.1016/S1005-0302(11)60094-7
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