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Brigatti, M. F., Galli, E., Medici, L. (1997) Ba-rich celestine: new data and crystal structure refinement. Mineralogical Magazine, 61 (406) 447-451 doi:10.1180/minmag.1997.061.406.10

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Reference TypeJournal (article/letter/editorial)
TitleBa-rich celestine: new data and crystal structure refinement
JournalMineralogical MagazineISSN0026-461X
AuthorsBrigatti, M. F.Author
Galli, E.Author
Medici, L.Author
Year1997 (June)Volume61
Issue406
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_61/61-406-447.pdf+
DOIdoi:10.1180/minmag.1997.061.406.10Search in ResearchGate
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Mindat Ref. ID183Long-form Identifiermindat:1:5:183:6
GUID0
Full ReferenceBrigatti, M. F., Galli, E., Medici, L. (1997) Ba-rich celestine: new data and crystal structure refinement. Mineralogical Magazine, 61 (406) 447-451 doi:10.1180/minmag.1997.061.406.10
Plain TextBrigatti, M. F., Galli, E., Medici, L. (1997) Ba-rich celestine: new data and crystal structure refinement. Mineralogical Magazine, 61 (406) 447-451 doi:10.1180/minmag.1997.061.406.10
In(1997, June) Mineralogical Magazine Vol. 61 (406) Mineralogical Society
Abstract/NotesAbstractA Ba-rich celestine (Sr0.87Ba0.13SO4) filling cavities of volcanoclastic rocks from Montecchio Maggiore (Vicenza, Italy) was studied. The role of the Ba content in the mineral was determined using X-ray powder data, single crystal X-ray refinement, thermal and chemical analyses. The unit cell parameters (obtained by single crystal diffraction) are a = 8.408, b = 5.372, c = 6.897 Ã…, and the refinement in the space group Pnma (Z = 4) gives the final R value of 0.039. The average (Sr,Ba)-oxygen bond length is 2.842 Ã… and agrees with an occupancy of Sr 87% and Ba 13%. Individual bond lengths (Sr,Ba)-O and bond strength calculations confirm that all twelve interactions are significant and define an irregular array around the cation.

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