Yu, Chun-Hua, Zhu, Run-Qiang, Jin, Yu, Liu, Ming-Liang, Jin, Lei (2013) Bis{tris[(1H-benzimidazol-3-ium-2-yl)methyl]amine} tetraaquaocta-μ2-chlorido-octachloridopentacadmate(II) monohydrate. Acta Crystallographica Section C Crystal Structure Communications, 69 (8) 811-814 doi:10.1107/s0108270113016557
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Bis{tris[(1H-benzimidazol-3-ium-2-yl)methyl]amine} tetraaquaocta-μ2-chlorido-octachloridopentacadmate(II) monohydrate | ||
| Journal | Acta Crystallographica Section C Crystal Structure Communications | ||
| Authors | Yu, Chun-Hua | Author | |
| Zhu, Run-Qiang | Author | ||
| Jin, Yu | Author | ||
| Liu, Ming-Liang | Author | ||
| Jin, Lei | Author | ||
| Year | 2013 (August 15) | Volume | 69 |
| Issue | 8 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s0108270113016557Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 191010 | Long-form Identifier | mindat:1:5:191010:4 |
| GUID | 0 | ||
| Full Reference | Yu, Chun-Hua, Zhu, Run-Qiang, Jin, Yu, Liu, Ming-Liang, Jin, Lei (2013) Bis{tris[(1H-benzimidazol-3-ium-2-yl)methyl]amine} tetraaquaocta-μ2-chlorido-octachloridopentacadmate(II) monohydrate. Acta Crystallographica Section C Crystal Structure Communications, 69 (8) 811-814 doi:10.1107/s0108270113016557 | ||
| Plain Text | Yu, Chun-Hua, Zhu, Run-Qiang, Jin, Yu, Liu, Ming-Liang, Jin, Lei (2013) Bis{tris[(1H-benzimidazol-3-ium-2-yl)methyl]amine} tetraaquaocta-μ2-chlorido-octachloridopentacadmate(II) monohydrate. Acta Crystallographica Section C Crystal Structure Communications, 69 (8) 811-814 doi:10.1107/s0108270113016557 | ||
| In | (2013, August) Acta Crystallographica Section C Crystal Structure Communications Vol. 69 (8) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | The title compound, (C24H24N7)2[Cd5Cl16(H2O)4]·H2O, contains a [Cd5Cl16(H2O)4]6−anion, two triply protonated tris[(1H-benzimidazol-3-ium-2-yl)methyl]amine cations and one solvent water molecule. The structure of the anion is a novel chloride-bridged pentanuclear cluster. The five unique CdIIcentres have quite different coordination environments. Two of the central hexacoordinated CdIIcations have a CdOCl5chromophore, in which each CdIIcation is ligated by four bridging chloride ligands, one terminal chloride ligand and one water molecule, adopting a distorted octahedral environment. The third central CdIIcation is octahedrally coordinated by four bridging chloride ligands and two water molecules. Finally, the two terminal CdIIcations are pentacoordinated by two bridging and three terminal chloride ligands and adopt a trigonal–bipyramidal geometry. A three-dimensional supramolecular network is formed through intra- and intermolecular O—H...O, O—H...Cl, N—H...Cl and N—H...O hydrogen bonds and π–π interactions between the cations and anions.<!?tpb=20.6pt> | ||
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