Sonar, Vijayakumar N., Parkin, Sean, Crooks, Peter A. (2012) OxycodoneN-oxide. Acta Crystallographica Section C Crystal Structure Communications, 68 (11) doi:10.1107/s0108270112040188
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | OxycodoneN-oxide | ||
| Journal | Acta Crystallographica Section C Crystal Structure Communications | ||
| Authors | Sonar, Vijayakumar N. | Author | |
| Parkin, Sean | Author | ||
| Crooks, Peter A. | Author | ||
| Year | 2012 (November 15) | Volume | 68 |
| Issue | 11 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s0108270112040188Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 191520 | Long-form Identifier | mindat:1:5:191520:8 |
| GUID | 0 | ||
| Full Reference | Sonar, Vijayakumar N., Parkin, Sean, Crooks, Peter A. (2012) OxycodoneN-oxide. Acta Crystallographica Section C Crystal Structure Communications, 68 (11) doi:10.1107/s0108270112040188 | ||
| Plain Text | Sonar, Vijayakumar N., Parkin, Sean, Crooks, Peter A. (2012) OxycodoneN-oxide. Acta Crystallographica Section C Crystal Structure Communications, 68 (11) doi:10.1107/s0108270112040188 | ||
| In | (2012, November) Acta Crystallographica Section C Crystal Structure Communications Vol. 68 (11) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | The title compound, (5R,9R,13S,14S,17R)-14-hydroxy-3-methoxy-17-methyl-4,5-epoxymorphinan-6-oneN-oxide, C18H21NO5, has been prepared in a diastereomerically pure form by the reaction of oxycodone with 3-chloroperbenzoic acid and subsequent crystallization of the product from chloroform. The crystal packing shows that the molecule exhibits intramolecular O—H...O [D...A= 2.482 (2) Å] hydrogen bonding. In addition, there are weak intermolecular C—H...O interactions which, along with van der Waals forces, stabilize the structure. The new chiral center at the 17-position is demonstrated to beR. | ||
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