Reference Type | Journal (article/letter/editorial) |
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Title | HRTEM observations of structural and chemical modulations in cosalite and its relationship to the lillianite homologues |
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Journal | Mineralogical Magazine |
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Authors | Pring, A. | Author |
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Etschmann, B. | Author |
Year | 2002 (June) | Volume | 66 |
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Issue | 3 |
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Publisher | Mineralogical Society |
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DOI | doi:10.1180/0026461026630041Search in ResearchGate |
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| Generate Citation Formats |
Mindat Ref. ID | 243362 | Long-form Identifier | mindat:1:5:243362:6 |
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GUID | 0 |
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Full Reference | Pring, A., Etschmann, B. (2002) HRTEM observations of structural and chemical modulations in cosalite and its relationship to the lillianite homologues. Mineralogical Magazine, 66 (3) 451-458 doi:10.1180/0026461026630041 |
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Plain Text | Pring, A., Etschmann, B. (2002) HRTEM observations of structural and chemical modulations in cosalite and its relationship to the lillianite homologues. Mineralogical Magazine, 66 (3) 451-458 doi:10.1180/0026461026630041 |
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Abstract/Notes | AbstractThe results of a HRTEM and electron diffraction investigation of a Cu- and Ag-rich cosalite, Cu1.2Ag0.9Pb6.7Bi8.2S20, from Ivigtut, Greenland, are presented. Electron diffraction patterns down [001] show pairs of satellite reflections at Gp±~1/8[140]* and Gp±~1/8[1̄40]* in addition to the strong Bragg reflections of the underlying average structure. The superlattice corresponds to a compositional and displacive modulation G±qprim where qprim is the primary modulation vector 1/8[140]*. The superlattice is attributed to coupled Ag/Pb/Bi and Cu/□ ordering and associated structural relaxation. The HRTEM images show a complex moire texture due to the structural modulations. Cosalite from Ivigtut, Greenland, also forms coherent intergrowths with members of the lillianite–gustavite series (Pb3Bi2S6–PbAgBi3S6). A model for the intergrowth between the structures is presented based on sharing both S and Pb atoms in the PbS-like slabs in both structures along [010]cosalite. |
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