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Mordberg, L. E., Stanley, C. J., Antonov, A. V. (2008) Polystage apatite recrystallization and svanbergite formation during weathering in an acid karstic environment. Mineralogical Magazine, 72 (1) 95-99 doi:10.1180/minmag.2008.072.1.95

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Reference TypeJournal (article/letter/editorial)
TitlePolystage apatite recrystallization and svanbergite formation during weathering in an acid karstic environment
JournalMineralogical Magazine
AuthorsMordberg, L. E.Author
Stanley, C. J.Author
Antonov, A. V.Author
Year2008 (February)Volume72
Issue1
PublisherMineralogical Society
DOIdoi:10.1180/minmag.2008.072.1.95Search in ResearchGate
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Mindat Ref. ID243904Long-form Identifiermindat:1:5:243904:8
GUID0
Full ReferenceMordberg, L. E., Stanley, C. J., Antonov, A. V. (2008) Polystage apatite recrystallization and svanbergite formation during weathering in an acid karstic environment. Mineralogical Magazine, 72 (1) 95-99 doi:10.1180/minmag.2008.072.1.95
Plain TextMordberg, L. E., Stanley, C. J., Antonov, A. V. (2008) Polystage apatite recrystallization and svanbergite formation during weathering in an acid karstic environment. Mineralogical Magazine, 72 (1) 95-99 doi:10.1180/minmag.2008.072.1.95
Abstract/NotesAbstractA Devonian weathering profile was developed near the contact of Riphean dolostone containing disseminated carbonate-fluorapatite and intensively pyritized black shales. Samples from the profile were investigated by XRF, SEM, electron microprobe and ion microprobe. Rock-forming minerals are apatite, diaspore, chlorite and kaolinite, while accessory minerals are svanbergite, anatase, pyrite and zircon.Primary marine carbonate-fluorapatite is represented by extremely weathered crystals concentrated near the footwall. Dissolution of apatite and pyrite provided an acidic environment that is expressed in the formation of S-rich apatite and svanbergite. The environment allowed Ti migration which formed anatase in weathered apatite grains. Coupled substitution Na+ + S6+ = Ca2+ + P5+ is suggested in S-rich apatite. A large volume of dissolved carbonate rocks was a source of Sr necessary for svanbergite formation. Apatite of the third generation formed at the final stage of weathering is represented by small (10—30 μm) very well shaped crystals.


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