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Bulanova, G. P., Griffin, W. L., Ryan, C. G. (1998) Nucleation environment of diamonds from Yakutian kimberlites. Mineralogical Magazine, 62 (3) 409-419 doi:10.1180/002646198547675

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Reference TypeJournal (article/letter/editorial)
TitleNucleation environment of diamonds from Yakutian kimberlites
JournalMineralogical MagazineISSN0026-461X
AuthorsBulanova, G. P.Author
Griffin, W. L.Author
Ryan, C. G.Author
Year1998 (June)Volume62
Issue3
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_62/62-3-409.pdf+
DOIdoi:10.1180/002646198547675Search in ResearchGate
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Mindat Ref. ID286Long-form Identifiermindat:1:5:286:2
GUID0
Full ReferenceBulanova, G. P., Griffin, W. L., Ryan, C. G. (1998) Nucleation environment of diamonds from Yakutian kimberlites. Mineralogical Magazine, 62 (3) 409-419 doi:10.1180/002646198547675
Plain TextBulanova, G. P., Griffin, W. L., Ryan, C. G. (1998) Nucleation environment of diamonds from Yakutian kimberlites. Mineralogical Magazine, 62 (3) 409-419 doi:10.1180/002646198547675
Abstract/NotesAbstractThe micro-inclusions located in the genetic centre of Yakutian diamond monocrystals have been studied using optical (anomalous birefringence, photoluminescence, cathodoluminescence) and microanalytical (electron-microprobe, proton-microprobe, scanning electron microscope) methods. Most diamonds nucleated heterogeneously on mineral seeds, that lowered the energy barrier to nucleation. Nucleation of peridotitic diamonds occurred on a matrix of graphite+iron+wüstite, in an environment dominated by forsteritic olivine and Fe-Ni sulfide. Nucleation of eclogitic diamonds occurred on a matrix of sulfide ± iron in an environment dominated by Fe-sulfide and omphacite (±-K-Na-Al-Si-melt). The mineral assemblages recorded in the central inclusions of Yakutian diamonds indicate that they grew in a reduced environment, with oxygen fugacity controlled by the iron-wüstite equilibrium. Nucleation of diamond occurred in the presence of a fluid, possibly a volatile-rich silicate melt, highly enriched in LIL (K, Ba, Rb, Sr) and HFSE (Nb, Ti, Zr) elements. This fluid also carried immiscible Fe-Ni-sulfide melts, and possibly a carbonatitic component; the introduction of this fluid into a reduced refractory environment may have been accompanied by a thermal pulse, and may have created the conditions necessary for the nucleation and growth of diamond.


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