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Akizuki, Mizuhiko, Hampar, Martin S., Zussman, Jack (1979) An explanation of anomalous optical properties of topaz. Mineralogical Magazine, 43 (326) 237-241 doi:10.1180/minmag.1979.043.326.05

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Reference TypeJournal (article/letter/editorial)
TitleAn explanation of anomalous optical properties of topaz
JournalMineralogical MagazineISSN0026-461X
AuthorsAkizuki, MizuhikoAuthor
Hampar, Martin S.Author
Zussman, JackAuthor
Year1979 (June)Volume43
Issue326
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_43/43-326-237.pdf+
DOIdoi:10.1180/minmag.1979.043.326.05Search in ResearchGate
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Mindat Ref. ID3016Long-form Identifiermindat:1:5:3016:2
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Full ReferenceAkizuki, Mizuhiko, Hampar, Martin S., Zussman, Jack (1979) An explanation of anomalous optical properties of topaz. Mineralogical Magazine, 43 (326) 237-241 doi:10.1180/minmag.1979.043.326.05
Plain TextAkizuki, Mizuhiko, Hampar, Martin S., Zussman, Jack (1979) An explanation of anomalous optical properties of topaz. Mineralogical Magazine, 43 (326) 237-241 doi:10.1180/minmag.1979.043.326.05
In(1979, June) Mineralogical Magazine Vol. 43 (326) Mineralogical Society
Abstract/NotesSummaryA study has been made of topaz crystals showing a sectoral texture related to the growth of the crystal, and showing anomalous optical properties within the sectors. The growth surfaces responsible for the development of most of the sectors have been identified. The fluorine/hydroxyl sites in topaz are symmetrically equivalent in the solid crystal, but at a growth surface this equivalence may be lost, resulting in a reduction in the crystal symmetry and the ordering of fluorine and hydroxyl, the ordering scheme being retained once the crystal has formed. The reduction in symmetry expected to be produced by this ordering is in general agreement with the actual reduction in symmetry indicated by the optical properties. Heating of the topaz to about 950 °C results in the almost complete disappearance of the optical anomalies due to disordering, which may be related to the loss of hydroxyl from the crystal. Anomalous pyro- and piezoelectric phenomena may also be the result of ordering. Published optical and X-ray determinative curves for fluorine in topaz may give erroneous results for ordered topaz.


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