| Reference Type | Journal (article/letter/editorial) |
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| Title | The crystal structure of caratiite |
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| Journal | Mineralogical Magazine | ISSN | 0026-461X |
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| Authors | Effenberger, Herta | Author |
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| Zemann, Josef | Author |
| Year | 1984 (December) | Volume | 48 |
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| Issue | 349 |
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| Publisher | Mineralogical Society |
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| Download URL | https://rruff.info/doclib/MinMag/Volume_48/48-349-541.pdf+ |
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| DOI | doi:10.1180/minmag.1984.048.349.10Search in ResearchGate |
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| Generate Citation Formats |
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| Mindat Ref. ID | 3670 | Long-form Identifier | mindat:1:5:3670:6 |
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| GUID | 0 |
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| Full Reference | Effenberger, Herta, Zemann, Josef (1984) The crystal structure of caratiite. Mineralogical Magazine, 48 (349) 541-546 doi:10.1180/minmag.1984.048.349.10 |
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| Plain Text | Effenberger, Herta, Zemann, Josef (1984) The crystal structure of caratiite. Mineralogical Magazine, 48 (349) 541-546 doi:10.1180/minmag.1984.048.349.10 |
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| In | (1984, December) Mineralogical Magazine Vol. 48 (349) Mineralogical Society |
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| Abstract/Notes | AbstractThe crystal structure of caratiite, K4Cu4O2 (SO4)4MeCl (a 13.60(2), c 4.98(1) Å, Z = 2) was solved in space group I4 from single crystal data, and refined to R = 0.035 for 654Fo > 6σ(Fo). The atomic arrangement is characterized by Cu2O(SO4)2 chains parallel to [001], with Cu in (4 + 1) co-ordination and O surrounded tetrahedrally by four Cu atoms. These chains are interconnected by K atoms to a framework, the channels of which house the Me and Cl atoms. The nature of the Me atoms is not completely clear; most probably the position is half occupied by Cu, fully occupied by Na, or occupied by a mixture of the two. |
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