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Mo, Juan, Qian, Heng-Yu, Du, Xiang-Dang, Chen, Wen (2006) catena-Poly[[[μ-pyridine-2-carbaldehyde azine-κ4 N,N′:N′′,N′′′-bis[(triphenylphosphine-κP)copper(I)]]-μ-1,2-bis(4-pyridyl)ethene-κ2 N:N′] bis(tetrafluoroborate)]. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s160053680600818x

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Titlecatena-Poly[[[μ-pyridine-2-carbaldehyde azine-κ4 N,N′:N′′,N′′′-bis[(triphenylphosphine-κP)copper(I)]]-μ-1,2-bis(4-pyridyl)ethene-κ2 N:N′] bis(tetrafluoroborate)]
JournalActa Crystallographica Section E Structure Reports Online
AuthorsMo, JuanAuthor
Qian, Heng-YuAuthor
Du, Xiang-DangAuthor
Chen, WenAuthor
Year2006 (April 1)Volume62
Issue4
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s160053680600818xSearch in ResearchGate
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Mindat Ref. ID460713Long-form Identifiermindat:1:5:460713:1
GUID0
Full ReferenceMo, Juan, Qian, Heng-Yu, Du, Xiang-Dang, Chen, Wen (2006) catena-Poly[[[μ-pyridine-2-carbaldehyde azine-κ4 N,N′:N′′,N′′′-bis[(triphenylphosphine-κP)copper(I)]]-μ-1,2-bis(4-pyridyl)ethene-κ2 N:N′] bis(tetrafluoroborate)]. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s160053680600818x
Plain TextMo, Juan, Qian, Heng-Yu, Du, Xiang-Dang, Chen, Wen (2006) catena-Poly[[[μ-pyridine-2-carbaldehyde azine-κ4 N,N′:N′′,N′′′-bis[(triphenylphosphine-κP)copper(I)]]-μ-1,2-bis(4-pyridyl)ethene-κ2 N:N′] bis(tetrafluoroborate)]. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s160053680600818x
In(2006, April) Acta Crystallographica Section E Structure Reports Online Vol. 62 (4) International Union of Crystallography (IUCr)
Abstract/NotesIn the title complex, {[Cu2(C12H10N2)(C12H10N4)(C18H15P)2](BF4)2}
n
, the cations form a linear chain, and are bridged by 1,2-bis(4-pyridyl)ethene and pyridine-2-carbaldehyde azine. Each CuI atom is coordinated by one P atom of a PPh3 ligand, two N atoms of a pyridine-2-carbaldehyde azine bridging ligand and one N atom of a bridging 1,2-bis(4-pyridyl)ethene ligand. There is a crystallographic centre of symmetry at the mid-point of the N—N bond.


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