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Puris, Eriks M., Wickham, Stephen M. (1994) Quantification of lower crustal synmetamorphic fluid fluxes in the Kapuskasing structural zone based on oxygen-isotope profiles across two paragneiss – mafic gneiss contacts. Canadian Journal of Earth Sciences, 31 (7) 1122-1133 doi:10.1139/e94-100

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Reference TypeJournal (article/letter/editorial)
TitleQuantification of lower crustal synmetamorphic fluid fluxes in the Kapuskasing structural zone based on oxygen-isotope profiles across two paragneiss – mafic gneiss contacts
JournalCanadian Journal of Earth Sciences
AuthorsPuris, Eriks M.Author
Wickham, Stephen M.Author
Year1994 (July 1)Volume31
Issue7
PublisherCanadian Science Publishing
DOIdoi:10.1139/e94-100Search in ResearchGate
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Mindat Ref. ID482511Long-form Identifiermindat:1:5:482511:5
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Full ReferencePuris, Eriks M., Wickham, Stephen M. (1994) Quantification of lower crustal synmetamorphic fluid fluxes in the Kapuskasing structural zone based on oxygen-isotope profiles across two paragneiss – mafic gneiss contacts. Canadian Journal of Earth Sciences, 31 (7) 1122-1133 doi:10.1139/e94-100
Plain TextPuris, Eriks M., Wickham, Stephen M. (1994) Quantification of lower crustal synmetamorphic fluid fluxes in the Kapuskasing structural zone based on oxygen-isotope profiles across two paragneiss – mafic gneiss contacts. Canadian Journal of Earth Sciences, 31 (7) 1122-1133 doi:10.1139/e94-100
In(1994, July) Canadian Journal of Earth Sciences Vol. 31 (7) Canadian Science Publishing
Abstract/Notes Detailed oxygen-isotope profiles were measured across two very similar amphibolite-grade, paragneiss – mafic gneiss contacts located 2 km apart within the Kapuskasing structural zone. The first profile is asymmetrical about die contact. δ18O values for whole rocks and minerals are homogeneous in the paragneiss (whole-rock δ18O = +10.4 to +11.4‰), smoothly decrease by about 2‰ over 2.5 m moving into the mafic gneiss, and are homogeneous in the remainder of the mafic gneiss (whole-rock δ18O = +7.0 to +7.4‰). The second profile is flat, with homogeneous whole-rock and mineral δ18O values in bom lithologies, and mafic gneiss values (whole-rock δ18O = +8.7 to +9.8‰) that are higher by about 3‰ relative to typical mafic gneiss values. Mineral–mineral isotopic fractioations are fairly constant in all samples and are typical of high-grade metamorphic rocks. Despite their differences, both profiles can be explained by the advection of a mixed H2O–CO2 fluid in equilibrium with the paragneiss across the contact into the mafic gneiss, coupled with diffusion of oxygen in the fluid. Modeling constrains the net fluid flux required to form me first profile to be 1–3 m3/m2, and for me second profile to be ≥ 10 m3/m2. Thus the net fluid flux during metamorphism varied probably by at least a factor of five over 2 km. These fluxes could have been generated locally within the Kapuskasing structural zone during metamorphism either by metamorphic devolatilization reactions or by the release of volatiles from crystallizing magmas.


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