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V. Stubičan, (1959) Residual hydroxyl groups in the metakaolin range. Mineralogical Magazine and Journal of the Mineralogical Society, 32 (244) 38-52 doi:10.1180/minmag.1959.032.244.06

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Reference TypeJournal (article/letter/editorial)
TitleResidual hydroxyl groups in the metakaolin range
JournalMineralogical Magazine and Journal of the Mineralogical Society
AuthorsV. Stubičan, Author
Year1959 (March)Volume32
Issue244
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_32/32-244-38.pdf+
DOIdoi:10.1180/minmag.1959.032.244.06
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Mindat Ref. ID5495Long-form Identifiermindat:1:5:5495:3
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Full ReferenceV. Stubičan, (1959) Residual hydroxyl groups in the metakaolin range. Mineralogical Magazine and Journal of the Mineralogical Society, 32 (244) 38-52 doi:10.1180/minmag.1959.032.244.06
Plain TextV. Stubičan, (1959) Residual hydroxyl groups in the metakaolin range. Mineralogical Magazine and Journal of the Mineralogical Society, 32 (244) 38-52 doi:10.1180/minmag.1959.032.244.06
In(1959) Mineralogical Magazine Vol. 32 (244) Mineralogical Society
Abstract/NotesSummaryInfra-red absorption spectroscopy has been used to study the retention of hydroxyl groups by kaolinite and halloysite after heat treatment in the range 600° C. to 850° C. Structurally disordered specimens initially lose water more rapidly than do ordered specimens, but retain hydroxyl groups at higher temperatures. Work on the phases obtained above 1100° C. is incomplete, but results for the lower temperatures indicate that the ordered structures tend to retain their atomic arrangement and form metakaolin, whereas disordered structures readily rearrange to yield γ-alumina, to the formation of which water is probably essential.


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