| Reference Type | Journal (article/letter/editorial) |
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| Title | Replacement of OH by OD in layer silicates, and identification of the vibrations of these groups in infra-red spectra |
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| Journal | Mineralogical Magazine |
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| Authors | Russell, J. D. | Author |
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| Farmer, V. C. | Author |
| Velde, B. | Author |
| Year | 1970 (December) | Volume | 37 |
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| Issue | 292 |
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| Publisher | Mineralogical Society |
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| Download URL | https://rruff.info/doclib/MinMag/Volume_37/37-292-869.pdf+ |
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| DOI | doi:10.1180/minmag.1970.037.292.01Search in ResearchGate |
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| Generate Citation Formats |
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| Mindat Ref. ID | 6403 | Long-form Identifier | mindat:1:5:6403:7 |
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| GUID | 0 |
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| Full Reference | Russell, J. D., Farmer, V. C., Velde, B. (1970) Replacement of OH by OD in layer silicates, and identification of the vibrations of these groups in infra-red spectra. Mineralogical Magazine, 37 (292) 869-879 doi:10.1180/minmag.1970.037.292.01 |
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| Plain Text | Russell, J. D., Farmer, V. C., Velde, B. (1970) Replacement of OH by OD in layer silicates, and identification of the vibrations of these groups in infra-red spectra. Mineralogical Magazine, 37 (292) 869-879 doi:10.1180/minmag.1970.037.292.01 |
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| In | (1970, December) Mineralogical Magazine Vol. 37 (292) Mineralogical Society |
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| Abstract/Notes | SummaryConditions necessary for exchange between lattice OH groups and D2O in expanding layer silicates are reported. From spectral changes in the 200β1200 cmβ1 region resulting from this exchange, in-plane librations of OH co-ordinated to (A1A1), (A1Mg), (A1Fe3+), and (MgMgMg) have been identified in montmorillonite, beidellite, saponite, hectorite, and vermiculite. Both in-plane and out-of-plane librations have been identified for pyrophyllite and celadonite, from comparison of synthetic specimens containing OD with natural or synthetic OH forms. Comparison of hydrogen and deuterium forms of Mg- and Ni-talcs leads to the identification of translational and librational OH vibrations. |
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