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Spearing-Ewyn, E. Anastasia K., Beattie, Nicholas A., Colebatch, Annie L., Martinez-Martinez, Antonio J., Docker, Andrew, Boyd, Timothy M., Baillie, Gregg, Reed, Rachel, Macgregor, Stuart A., Weller, Andrew S. (2019) The role of neutral Rh(PONOP)H, free NMe2H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η2-H2)]+ catalyst. Dalton Transactions, 48 (39). 14724-14736 doi:10.1039/c9dt03358k

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Reference TypeJournal (article/letter/editorial)
TitleThe role of neutral Rh(PONOP)H, free NMe2H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η2-H2)]+ catalyst
JournalDalton Transactions
AuthorsSpearing-Ewyn, E. Anastasia K.Author
Beattie, Nicholas A.Author
Colebatch, Annie L.Author
Martinez-Martinez, Antonio J.Author
Docker, AndrewAuthor
Boyd, Timothy M.Author
Baillie, GreggAuthor
Reed, RachelAuthor
Macgregor, Stuart A.Author
Weller, Andrew S.Author
Year2019Volume48
Issue39
PublisherRoyal Society of Chemistry (RSC)
DOIdoi:10.1039/c9dt03358kSearch in ResearchGate
Generate Citation Formats
Mindat Ref. ID8366972Long-form Identifiermindat:1:5:8366972:1
GUID0
Full ReferenceSpearing-Ewyn, E. Anastasia K., Beattie, Nicholas A., Colebatch, Annie L., Martinez-Martinez, Antonio J., Docker, Andrew, Boyd, Timothy M., Baillie, Gregg, Reed, Rachel, Macgregor, Stuart A., Weller, Andrew S. (2019) The role of neutral Rh(PONOP)H, free NMe2H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η2-H2)]+ catalyst. Dalton Transactions, 48 (39). 14724-14736 doi:10.1039/c9dt03358k
Plain TextSpearing-Ewyn, E. Anastasia K., Beattie, Nicholas A., Colebatch, Annie L., Martinez-Martinez, Antonio J., Docker, Andrew, Boyd, Timothy M., Baillie, Gregg, Reed, Rachel, Macgregor, Stuart A., Weller, Andrew S. (2019) The role of neutral Rh(PONOP)H, free NMe2H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η2-H2)]+ catalyst. Dalton Transactions, 48 (39). 14724-14736 doi:10.1039/c9dt03358k
In(2019) Dalton Transactions Vol. 48 (39) Royal Society of Chemistry (RSC)

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Johnson, Alice, Martínez-Martínez, Antonio J., Macgregor, Stuart A., Weller, Andrew S. (2019) A d10 Ag(i) amine–borane σ-complex and comparison with a d8 Rh(i) analogue: structures on the η1 to η2:η2 continuum. Dalton Transactions, 48 (26). 9776-9781 doi:10.1039/c9dt00971j
Johnson, Alice, Royle, Cameron G., Brodie, Claire N., Martínez-Martínez, Antonio J., Duckett, Simon B., Weller, Andrew S. (2021) η2-Alkene Complexes of [Rh(PONOP-iPr)(L)]+ Cations (L = COD, NBD, Ethene) Intramolecular Alkene-Assisted Hydrogenation and Dihydrogen Complex [Rh(PONOP-iPr)(η-H2)]+. Inorganic Chemistry, 60 (18) 13903-13912 doi:10.1021/acs.inorgchem.0c03687
Adams, Gemma M., Colebatch, Annie L., Skornia, Joseph T., McKay, Alasdair I., Johnson, Heather C., Lloyd−Jones, Guy C., Macgregor, Stuart A., Beattie, Nicholas A., Weller, Andrew S. (2018) Dehydropolymerization of H3B·NMeH2 To Form Polyaminoboranes Using [Rh(Xantphos-alkyl)] Catalysts. Journal Of The American Chemical Society, 140 (4) 1481-1495 doi:10.1021/jacs.7b11975
Colebatch, Annie L., McKay, Alasdair I., Beattie, Nicholas A., Macgregor, Stuart A., Weller, Andrew S. (2017) Fluoroarene Complexes with Small Bite Angle Bisphosphines: Routes to Amine-Borane and Aminoborylene Complexes. European Journal of Inorganic Chemistry, 2017 (38) 4533-4540 doi:10.1002/ejic.201700600
Huertos, Miguel A., Weller, Andrew S. (2012) Intermediates in the Rh-catalysed dehydrocoupling of phosphine–borane. Chemical Communications, 48 (57). 7185pp. doi:10.1039/c2cc32696e
Gyton, Matthew R., Hood, Thomas M., Chaplin, Adrian B. (2019) A convenient method for the generation of {Rh(PNP)}+ and {Rh(PONOP)}+ fragments: reversible formation of vinylidene derivatives. Dalton Transactions, 48 (9). 2877-2880 doi:10.1039/c8dt05049j
Hooper, Thomas N., Weller, Andrew S., Beattie, Nicholas A., Macgregor, Stuart A. (2016) Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies. Chemical Science, 7. 2414-2426 doi:10.1039/c5sc04150c
Hooper, Thomas N., Weller, Andrew S., Beattie, Nicholas A., Macgregor, Stuart A. (2016) Correction: Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies. Chemical Science, 7. 2437 doi:10.1039/c6sc90014c
McKay, Alasdair I., Krämer, Tobias, Rees, Nicholas H., Thompson, Amber L., Christensen, Kirsten E., Macgregor, Stuart A., Weller, Andrew S. (2017) Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]. Organometallics, 36. 22-25 doi:10.1021/acs.organomet.6b00645
Sewell, Laura J., Huertos, Miguel A., Dickinson, Molly E., Weller, Andrew S., Lloyd-Jones, Guy C. (2013) Dehydrocoupling of Dimethylamine Borane Catalyzed by Rh(PCy3)2H2Cl. Inorganic Chemistry, 52 (8) 4509-4516 doi:10.1021/ic302804d
Kumar, Amit, Beattie, Nicholas A., Pike, Sebastian D., Macgregor, Stuart A., Weller, Andrew S. (2016) The Simplest Amino-borane H2 B=NH2 Trapped on a Rhodium Dimer: Pre-Catalysts for Amine-Borane Dehydropolymerization. Angewandte Chemie, 128 (23). 6763-6768 doi:10.1002/ange.201600898
 
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