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Nkabyo, Henry A., Procacci, Barbara, Duckett, Simon B., Koch, Klaus R. (2019) Reversible photo-isomerization of cis-[Pd(L-κS,O)2] (HL = N,N-diethyl-N′-1-naphthoylthiourea) to trans-[Pd(L-κS,O)2] and the unprecedented formation of trans-[Pd(L-κS,N)2] in solution. Dalton Transactions, 48 (46). 17241-17251 doi:10.1039/c9dt03672e

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Reference TypeJournal (article/letter/editorial)
TitleReversible photo-isomerization of cis-[Pd(L-κS,O)2] (HL = N,N-diethyl-N′-1-naphthoylthiourea) to trans-[Pd(L-κS,O)2] and the unprecedented formation of trans-[Pd(L-κS,N)2] in solution
JournalDalton Transactions
AuthorsNkabyo, Henry A.Author
Procacci, BarbaraAuthor
Duckett, Simon B.Author
Koch, Klaus R.Author
Year2019Volume48
Issue46
PublisherRoyal Society of Chemistry (RSC)
DOIdoi:10.1039/c9dt03672eSearch in ResearchGate
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Mindat Ref. ID8367666Long-form Identifiermindat:1:5:8367666:0
GUID0
Full ReferenceNkabyo, Henry A., Procacci, Barbara, Duckett, Simon B., Koch, Klaus R. (2019) Reversible photo-isomerization of cis-[Pd(L-κS,O)2] (HL = N,N-diethyl-N′-1-naphthoylthiourea) to trans-[Pd(L-κS,O)2] and the unprecedented formation of trans-[Pd(L-κS,N)2] in solution. Dalton Transactions, 48 (46). 17241-17251 doi:10.1039/c9dt03672e
Plain TextNkabyo, Henry A., Procacci, Barbara, Duckett, Simon B., Koch, Klaus R. (2019) Reversible photo-isomerization of cis-[Pd(L-κS,O)2] (HL = N,N-diethyl-N′-1-naphthoylthiourea) to trans-[Pd(L-κS,O)2] and the unprecedented formation of trans-[Pd(L-κS,N)2] in solution. Dalton Transactions, 48 (46). 17241-17251 doi:10.1039/c9dt03672e
In(2019) Dalton Transactions Vol. 48 (46) Royal Society of Chemistry (RSC)

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Nkabyo, Henry A., Koch, Klaus R. (2018) New trans-[Pd(L-κS,O)2] complexes from N,N-dialkyl-N′-aroylthioureas prepared by photo-induced isomerization of their cis-[Pd(L-κS,O)2] counterparts and their thermal trans-cis isomerization. Inorganica Chimica Acta, 483. 440-447 doi:10.1016/j.ica.2018.08.028
Nkabyo, Henry A., Procacci, Barbara, Duckett, Simon B., Koch, Klaus R. (2020) Understanding the mechanism of cis–trans isomerism in photo-active palladium(II) complexes derived from the N,N-di-substituted benzoylthioureas. Inorganica Chimica Acta, 512. 119884pp. doi:10.1016/j.ica.2020.119884
Kotzé, Izak A., Smith, Vincent J., Kangara, Edmore F., Koch, Klaus R. (2017) Rare, hypodentate L-κS coordination mode of N,N-dialkyl-N′-aroylthioureas leads to unprecedented mixed-ligand [Pt(phen)(L-κS)2] complexes. New Journal of Chemistry, 41. 14995-15002 doi:10.1039/c7nj03178e
Nkabyo, H.A., Koch, K.R. (2019) Configurational E/Z and photo-induced cis-trans isomerism in the Pd(II) complex of asymmetrical N,N-methyl-ethyl-N′-benzoylthiourea. Journal of Molecular Structure, 1190. 47-53 doi:10.1016/j.molstruc.2019.04.038
Barnard, Ilse, Koch, Klaus R (2019) 59Co NMR, a facile tool to demonstrate EEE, EEZ, EZZ and ZZZ configurational isomerism in fac-[Co(L-κS,O)3] complexes derived from asymmetrically substituted N,N-dialkyl-N′-aroylthioureas. Inorganica Chimica Acta, 495. 119019pp. doi:10.1016/j.ica.2019.119019
Westra, Arjan N., Esterhuysen, Catharine, Koch, Klaus R. (2004) Intramolecular hydrogen-bond-directed coordination:trans-bis(N-benzoyl-N′-propylthiourea-κS)diiodoplatinum(II) andtrans-bis(N-benzoyl-N′-propylthiourea-κS)dibromoplatinum(II) Acta Crystallographica Section C Crystal Structure Communications, 60 (8) doi:10.1107/s0108270104014933
Serrano-Ruiz, Manuel, Lorenzo-Luis, Pablo, Romerosa, Antonio, Mena-Cruz, Adrian (2013) Catalytic isomerization of allylic alcohols in water by [RuClCp(PTA)2], [RuClCp(HPTA)2]Cl2·2H2O, [RuCp(DMSO-κS)(PTA)2]Cl, [RuCp(DMSO-κS)(PTA)2](OSO2CF3) and [RuCp(DMSO-κS)(HPTA)2]Cl3·2H2O. Dalton Transactions, 42 (21). 7622pp. doi:10.1039/c3dt32998d
Pahari, D., Jain, V. K., Tiekink, E. R. T. (2000) Crystal structure of bis(O,O-diisopropylphosphorodithioato-κS,κS’)-bίs[μ-[2-(mercaptoο-κS)ethoxy-κΟ]ethanethiolato(-2)κS:κS]-diindium,[(iPrO)2PS2In(SCH2CH2OCH2CH2S)2InS2P(OiPr)2]. Zeitschrift für Kristallographie - New Crystal Structures, 215 (3) doi:10.1515/ncrs-2000-0369
Bitzer, Rodrigo S., Nascimento, Marco A.C., Filgueiras, Carlos A.L. (2015) A contribution to the coordination chemistry of (E)-N,N′-bis(2-pyridyl)iminoisoindoline (2-pyimiso): Synthesis, characterization, and DFT calculations of trans-[PtCl2(dmso-κS)(2-pyimiso-κN)]. Polyhedron, 102. 329-336 doi:10.1016/j.poly.2015.09.064
Nkabyo, Henry A., Luckay, Robert C., Koch, Klaus R. (2020) Photo-isomerization of palladium(II) N,N-di-substituted acylthioureas: The role of free ligands and formation of mixed-ligand complexes. Inorganic Chemistry Communications, 119. 108035pp. doi:10.1016/j.inoche.2020.108035
Fackler, John P., Thompson, Loren D. (1981) Sulfur chelates 36. Structural characterization of the Trans isomers of the O-ethylphenyldithiophosphonates of Pd(II) and Pt(II), M[S2P(OC2H5)C6H5]2. Cis-Trans isomerization of the planar Pd(II) complex. Inorganica Chimica Acta, 48. 45-52 doi:10.1016/s0020-1693(00)90064-1
 
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