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Berthierite

A valid IMA mineral species - grandfathered
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02866600017271921414105.jpg
Berthierite

Gründenwald, St Ulrich, Bollschweil, Breisgau-Hochschwarzwald, Freiburg Region, Baden-Württemberg, Germany
01650590017271921479561.jpg
Berthierite, etc.

Herja Mine, Baia Mare, Maramureș County, Romania
08748770017548403196890.jpg
Berthierite

Puits Giraudet, Nades mines, Nades, Vichy, Allier, Auvergne-Rhône-Alpes, France
02866600017271921414105.jpg
Berthierite

Gründenwald, St Ulrich, Bollschweil, Breisgau-Hochschwarzwald, Freiburg Region, Baden-Württemberg, Germany
01650590017271921479561.jpg
Berthierite, etc.

Herja Mine, Baia Mare, Maramureș County, Romania
07127980017547331475253.jpg
Berthierite

Puits Giraudet, Nades mines, Nades, Vichy, Allier, Auvergne-Rhône-Alpes, France
02866600017271921414105.jpg
Berthierite

Gründenwald, St Ulrich, Bollschweil, Breisgau-Hochschwarzwald, Freiburg Region, Baden-Württemberg, Germany
04243840017271921533347.jpg
Berthierite, etc.

Herja Mine, Baia Mare, Maramureș County, Romania
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About BerthieriteHide

00459640017271921546869.jpg
Pierre Berthier
Formula:
FeSb2S4
Colour:
Dark steel-grey, often with iridescent tarnish.
Lustre:
Metallic
Hardness:
2 - 3
Specific Gravity:
4.64
Crystal System:
Orthorhombic
Name:
Named in 1827 by Wilhelm Karl von Haidinger in honor of Pierre Berthier [July 3, 1782, Nemours, Seine-et-Marne, France – August 24, 1861, France], French chemist and mineralogist at the École des Mines, and also Inspector of Mines during his career. He named a number of species including chamosite, franklinite, halloysite, and nontronite. He is well-known for his study of bauxite. The mineral berthierine is also named after him.
Berthierite is a relatively rare ore mineral because it is only stable over extremely narrow intervals of fO2 and fS2 (Williams-Jones and Normand, 1997).


Unique IdentifiersHide

Mindat ID:
640
Long-form identifier:
mindat:1:1:640:8

IMA Classification of BerthieriteHide

IMA status:
Approved, 'Grandfathered' (first described prior to 1959)

Classification of BerthieriteHide

Strunz-mindat (2025):
2.HA.20

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
A : With Cu, Ag, Fe (without Pb)
Dana 7th ed.:
3.7.9.3
Dana 8th ed.:
3.7.9.3

3 : SULFOSALTS
7 : ø = 2
Hey's CIM Ref.:
5.8.4

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
8 : Sulpharsenites etc. of Mn, Fe, Co and Ni

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
BtrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
BtrThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of BerthieriteHide

Lustre:
Metallic
Transparency:
Opaque
Colour:
Dark steel-grey, often with iridescent tarnish.
Streak:
Dark brownish-grey.
Hardness:
2 - 3 on Mohs scale
Hardness Data:
Measured
Tenacity:
Brittle
Cleavage:
Poor/Indistinct
Indistinct prismatic.
Fracture:
Irregular/Uneven, Splintery
Density:
4.64 g/cm3 (Measured)    4.66 g/cm3 (Calculated)

Optical Data of BerthieriteHide

Anisotropism:
Very strong
Reflectivity:
WavelengthR1 (%)R2 (%)
400nm32.6% 46.2%
420nm32.2% 45.9%
440nm31.8% 45.5%
460nm31.2% 45.0%
480nm30.7% 44.4%
500nm30.4% 43.8%
520nm30.2% 43.1%
540nm30.3% 42.5%
560nm30.4% 41.9%
580nm30.8% 41.4%
600nm31.1% 40.8%
620nm31.4% 40.3%
640nm31.4% 39.9%
660nm31.4% 39.4%
680nm31.4% 38.9%
700nm31.3% 38.4%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 46.2%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Grey
Pleochroism:
Visible
Comments:
Markedly pleochroic.

Chemistry of BerthieriteHide

Mindat Formula:
FeSb2S4
Element Weights:
Element% weight
Sb56.947 %
S29.994 %
Fe13.059 %

Calculated from ideal end-member formula.
Elements listed:
Fe, S, Sb - search for minerals with similar chemistry
Common Impurities:
Mn,Cu,Pb,Ag

Crystallography of BerthieriteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Cell Parameters:
a = 11.44 Å, b = 14.12 Å, c = 3.76 Å
Ratio:
a:b:c = 0.81 : 1 : 0.266
Unit Cell V:
607.36 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Prismatic on, and striated parallel to [001]. Prismatic to fibrous massive, plumose, radial; granular.
Comment:
sp. gr. Pnam

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000014BerthieriteBuerger M J (1936) The crystal structure of berthierite American Mineralogist 21 205-20619360293
0000064BerthieriteBuerger M J, Hahn T (1954) The crystal structure of berthierite, FeSb2S4 American Mineralogist 39 319-31919540293
0000069BerthieriteBuerger M J, Hahn T (1955) The crystal structure of berthierite, FeSb2S4 American Mineralogist 40 226-23819550293
0019205BerthieritePeriotto B, Balic-Zunic T, Nestola F (2012) The role of the Sb3+ lone-electron pairs and Fe2+ coordination in the high-pressure behavior of berthierite the Baia Mare metallogenic area, Romania The Canadian Mineralogist 50 201-2182012hydro-thermal vein-type deposit of Herja in0.0001293
0019206BerthieritePeriotto B, Balic-Zunic T, Nestola F (2012) The role of the Sb3+ lone-electron pairs and Fe2+ coordination in the high-pressure behavior of berthierite the Baia Mare metallogenic area, Romania The Canadian Mineralogist 50 201-2182012hydro-thermal vein-type deposit of Herja in1.41293
0019207BerthieritePeriotto B, Balic-Zunic T, Nestola F (2012) The role of the Sb3+ lone-electron pairs and Fe2+ coordination in the high-pressure behavior of berthierite the Baia Mare metallogenic area, Romania The Canadian Mineralogist 50 201-2182012hydro-thermal vein-type deposit of Herja in2.63293
0019208BerthieritePeriotto B, Balic-Zunic T, Nestola F (2012) The role of the Sb3+ lone-electron pairs and Fe2+ coordination in the high-pressure behavior of berthierite the Baia Mare metallogenic area, Romania The Canadian Mineralogist 50 201-2182012hydro-thermal vein-type deposit of Herja in3.72293
0019209BerthieritePeriotto B, Balic-Zunic T, Nestola F (2012) The role of the Sb3+ lone-electron pairs and Fe2+ coordination in the high-pressure behavior of berthierite the Baia Mare metallogenic area, Romania The Canadian Mineralogist 50 201-2182012hydro-thermal vein-type deposit of Herja in4.89293
0019210BerthieritePeriotto B, Balic-Zunic T, Nestola F (2012) The role of the Sb3+ lone-electron pairs and Fe2+ coordination in the high-pressure behavior of berthierite the Baia Mare metallogenic area, Romania The Canadian Mineralogist 50 201-2182012hydro-thermal vein-type deposit of Herja in6.62293
0019211BerthieritePeriotto B, Balic-Zunic T, Nestola F (2012) The role of the Sb3+ lone-electron pairs and Fe2+ coordination in the high-pressure behavior of berthierite the Baia Mare metallogenic area, Romania The Canadian Mineralogist 50 201-2182012hydro-thermal vein-type deposit of Herja in7.41293
0010254BerthieriteLemoine P, Carre D, Robert F (1991) Structure du sulfure de fer et d'antimoine, FeSb2S4 (Berthierite) Acta Crystallographica C47 938-94019910293
0010987BerthieriteBente K, Edenharter A (1989) Rontgenographische strukturanalyse von MnSb2S4 und strukturverfeinerung von berthierit, FeSb2S4 Zeitschrift fur Kristallographie 185 31-3319890293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.07 Å(20)
6.00 Å(4)
5.692 Å(4)
5.276 Å(6)
4.350 Å(4)
3.663 Å(90)
3.628 Å(50)
3.531 Å(20)
3.458 Å(25)
3.378 Å(40)
3.181 Å(75)
3.059 Å(30)
2.999 Å(50)
2.953 Å(10)
2.862 Å(80)
2.621 Å(95)
2.601 Å(100)
2.531 Å(30)
2.509 Å(18)
2.498 Å(25)
2.353 Å(4)
2.345 Å(8)
2.322 Å(20)
2.305 Å(8)
2.267 Å(18)
2.261 Å(14)
2.239 Å(25)
2.214 Å(18)
2.168 Å(30)
2.161 Å(30)
2.129 Å(4)
2.099 Å(6)
2.044 Å(35)
2.005 Å(20)
2.001 Å(20)
1.988 Å(2)
1.941 Å(6)
Comments:
ICDD 24-509. Synthetic.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Geological Setting:
Low-temperature hydrothermal veins rich in antimony and deficient in sulfur

Type Occurrence of BerthieriteHide

Synonyms of BerthieriteHide

Other Language Names for BerthieriteHide

Relationship of Berthierite to other SpeciesHide

Member of:
Berthierite Group
Other Members of Berthierite Group:
CleriteMnSb2S4Orth. mmm (2/m 2/m 2/m)
GaravelliteFeSbBiS4Orth.
Structurally related to group(s):
Meneghinite Homologous SeriesSeveral synthetic homologues are known.

Common AssociatesHide

Associated Minerals Based on Photo Data:
57 photos of Berthierite associated with StibniteSb2S3
51 photos of Berthierite associated with SideriteFeCO3
41 photos of Berthierite associated with QuartzSiO2
26 photos of Berthierite associated with CalciteCaCO3
24 photos of Berthierite associated with JamesonitePb4FeSb6S14
18 photos of Berthierite associated with BoulangeritePb5Sb4S11
14 photos of Berthierite associated with ChalcostibiteCuSbS2
14 photos of Berthierite associated with PyriteFeS2
11 photos of Berthierite associated with Native AntimonySb
10 photos of Berthierite associated with PyrrhotiteFe1-xS

Related Minerals - Strunz-mindat GroupingHide

2.HA.05GrundmanniteCuBiSe2Orth. mmm (2/m 2/m 2/m) : Pnma
2.HA.05EmplectiteCuBiS2Orth. mmm (2/m 2/m 2/m) : Pmna
2.HA.05PříbramiteCuSbSe2Orth. mmm (2/m 2/m 2/m) : Pnma
2.HA.05Hansblockite(Cu,Hg)(Bi,Pb)Se2Mon. 2/m : P21/b
2.HA.05ChalcostibiteCuSbS2Orth. mmm (2/m 2/m 2/m)
2.HA.10MiargyriteAgSbS2Mon. 2/m : B2/b
2.HA.20SunshuiteMon. 2/m : B2/m
2.HA.20GaravelliteFeSbBiS4Orth.
2.HA.20GraţianiteMnBi2S4Mon. 2/m : B2/m
2.HA.20CleriteMnSb2S4Orth. mmm (2/m 2/m 2/m)
2.HA.25AramayoiteAg3Sb2(Bi,Sb)S6Tric. 1 : P1
2.HA.25BaumstarkiteAg3Sb3S6Tric. 1 : P1
2.HA.30ZhonghongiteCu29(As,Sb)12S33Orth. mm2 : Fmm2

Fluorescence of BerthieriteHide

In UV light:
Not fluorescent in UV.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BerthieriteHide

References for BerthieriteHide

Reference List:
Berthier, P. (1827) Haidingerite, minerai d'antimoine d'Auvergne d'espece nouvelle. Annales de chimie et de physique: 35: 351-359 (as Haidingerite).
Berthier, P. (1827) Der Berthierit, eine neue Mineralspecies. Annalen der Physik: 11: 478-482. (as Haidingerite)
Haidinger, W. (1827) On berthierite, a new mineral species. The Edinburgh Journal of Science, 7, 353-354.
Groth (1874) 16: 80 (as Eisenantimonglanz).
Loczka, Josef (1903) Ueber den Berthierit von Bräunsdorf. Zeitschrift für Kristallographie, 37 (1). 379-385 doi:10.1524/zkri.1903.37.1.379
Ungemach, Henri (1906) Les gîtes métallifères du Val de Villé (Alsace). Bulletin de Minéralogie, 29 (5). 194-282 doi:10.3406/bulmi.1906.2780
Doelter (1926) 4(1): 586.
Stillwell, F. L. (1926) On the nature of Berthierite. Mineralogical Magazine and Journal of the Mineralogical Society, 21 (114) 83-86 doi:10.1180/minmag.1926.021.114.03
Krenner (1928) Centralblatt für Mineralogie: 265.
Krenner, J. (1928) Berthierit Felsőbányáról. Mathematikai és Természettudományi Értesítő, 45, 13-14.
Zsivny, Victor, Zombory, László (1934) Berthierite from Kisbánya, Carpathians. Mineralogical Magazine and Journal of the Mineralogical Society, 23 (145) 566-568 doi:10.1180/minmag.1934.023.145.05
Buerger, M.J. (1936) The crystal structure of berthierite. American Mineralogist: 21: 205-206. (abstract)
Buerger, M. J. (1936) Crystallographic data, unit cell and space group for berthierite (FeSb2S4). American Mineralogist, 21 (7). 442-448
Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.pp.481-482
Buerger, M. J., Hahn, Theodor (1955) The crystal structure of berthierite, FeSb2S4. American Mineralogist, 40 (3-4) 226-238
Ramdohr, Paul (1969) The Ore Minerals and their Intergrowths. Pergamon Press, Oxford. 1174pp. doi:10.1016/c2013-0-10027-x
Barton, Paul B. (1971) The Fe-Sb-S system. Economic Geology, 66 (1) 121-132 doi:10.2113/gsecongeo.66.1.121
Tatsuka, Kiyoaki, Morimoto, Nobuo (1977) Tetrahedrite stability relations in the Cu-Fe-Sb-S system. American Mineralogist, 62 (11-12) 1101-1109
Bente, K., Edenharter, A. (1989) Röntgenographische Strukturanalyse von MnSb2S4 und Strukturverfeinerung von Berthierit, FeSb2S4. Zeitschrift für Kristallographie, 185, 31-33.
Lemoine, P.; Carré, D.; Robert, F. (1991) Structure du sulfure de fer et d'antimoine, FeSb2S4 (berthiérite). Acta Crystallographica Section C Crystal Structure Communications, 47 (5). 938-940 doi:10.1107/s0108270190012124
Williams-Jones, Anthony E., Norman, Charles (1997) Controls of mineral parageneses in the system Fe-Sb-S-O. Economic Geology, 92 (3) 308-324 doi:10.2113/gsecongeo.92.3.308
Łukaszewicz, K., Pietraszko, A., Stępień-Damm, J., Kajokas, A., Grigas, J., Drulis, H. (2001) Crystal Structure, Mössbauer Spectra, Thermal Expansion, and Phase Transition of Berthierite FeSb2S4. Journal of Solid State Chemistry, 162. 79-83 doi:10.1006/jssc.2001.9347
(2005) Berthierite. Handbook of Mineralogy. Mineralogical Society of America
Kharbish, S., P. Andráš, (2014) Investigations of the Fe sulfosalts berthierite, garavellite, arsenopyrite and gudmundite by Raman spectroscopy. Mineralogical Magazine, 78 (5) 1287-1299 doi:10.1180/minmag.2014.078.5.13

Localities for BerthieriteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • Jujuy Province
    • Rinconada Department
Coira et al. (1995) +1 other reference
  • Santa Cruz Province
    • Río Chico Department
      • Gobernador Gregores
Brodtkorb (2002)
Australia
 
  • New South Wales
    • Dudley Co.
Gilligan et al. (1992)
    • Fitzroy Co.
      • Paddys Plain
Gilligan et al. (1992)
Gilligan et al. (1992) +1 other reference
Gilligan et al. (1992)
    • Raleigh Co.
      • Urunga
Gilligan et al. (1992)
Gilligan et al. (1992)
    • Sandon Co.
Gilligan et al. (1992)
      • Armidale
Gilligan et al. (1992)
      • Conningdale
Gilligan et al. (1992)
Ashley et al. (2000)
Gilligan et al. (1992)
        • Becks Point
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
Gilligan et al. (1992)
      • Metz
Gilligan et al. (1992)
Gilligan et al. (1992)
      • Tilbuster
Gilligan et al. (1992)
Gilligan et al. (1992)
    • Yancowinna Co.
      • Broken Hill district
Ramdohr (1950) +1 other reference
Teals et al. (2006)
  • Tasmania
    • Waratah-Wynyard municipality
      • Waratah district
        • Waratah
Bottrill et al. (2008) +1 other reference
  • Victoria
    • East Gippsland Shire
      • Glen Wills
        • Sunnyside goldfield
    • Loddon Shire
      • Inglewood
Birch (2015)
    • Yarra Ranges Shire
I.M. Threadgold (1958)
  • Western Australia
    • Cue Shire
      • Cue
Mock (1987)
Austria
 
  • Burgenland
    • Oberwart District
      • Stadtschlaining
Huber et al. (1981) +1 other reference
  • Carinthia
    • Sankt Veit an der Glan District
      • Friesach
        • Zeltschach
Blaß et al. (2002)
    • Spittal an der Drau District
      • Kleblach-Lind
        • Leßnig
Mali (1996)
Collection of NHM
  • Salzburg
    • Zell am See District
      • Mittersill
Strasser (1989)
Meixner (1980)
  • Tyrol
    • Lienz District
Exel (1993)
Mali (1996)
      • Nikolsdorf
Günter Grundmann collection
      • Obertilliach
        • Leiten
      • Strassen
Tornquist (1935)
Bolivia
 
  • La Paz
    • Larecaja Province
      • Sorata
Federico Ahlfeld and Alejandro Schneider-Scherbina (1964)
  • Oruro
    • Pantaleón Dalence Province
      • Santa Fé mining district
Dill et al. (1997) +1 other reference
  • Potosí
    • Antonio Quijarro Province
Dill et al. (1997) +1 other reference
    • Tomás Frías Province
Dill et al. (1997) +1 other reference
Bosnia and Herzegovina
 
  • Federation of Bosnia and Herzegovina
    • Central Bosnia Canton
      • Fojnica
Ljudevit Barić +1 other reference
  • Republika Srpska
    • Srebrenica
Radosavljević et al. (2016)
Radosavljevic et al. (2005)
Brazil
 
  • Minas Gerais
    • Mariana
      • Passagem de Mariana
Oberthür et al. (2008)
    • Santa Bárbara
Lobato et al. (2001) +1 other reference
Bulgaria
 
  • Blagoevgrad Province
    • Garmen Municipality
R.Kostov. 1979. Berthierite from Ribnovo
Canada
 
  • British Columbia
    • Atlin Mining Division
      • Tagish Lake
Mauthner et al. (1996)
    • New Westminster Mining Division
      • Sumallo River
Peatfield (n.d.)
    • Skeena Mining Division
Montgomery (n.d.)
  • New Brunswick
    • Kings Co.
      • Springfield Parish
Heidarian (2022)
    • York Co.
      • Clarence Stream area
Cabri et al. (2007) +2 other references
      • Prince William Parish
        • Lake George
Wilson (1991)
  • Northwest Territories
    • North Slave Region
Coleman (1953)
Coleman (1953)
  • Nova Scotia
    • Hants Co.
      • West Gore
Kontak et al. (1996)
  • Ontario
    • Kenora District
      • Balmer Township
Rocks & Minerals 79:2 pp94-99
      • Dome Township
Can. Rockhound: 7 (1)
    • Lanark County
      • Lavant Township
Traill (1983)
    • Sudbury District
      • Unorganized North Sudbury District
        • Sewell Township
Sabina (1974)
    • Thunder Bay District
      • Bomby Township
Harris et al. (1988)
Sabina (1991)
Patterson (1984)
      • Errington Township
Armstrong (1944)
  • Québec
    • Abitibi-Témiscamingue
      • La Vallée-de-l'Or RCM
        • Val d'Or
Jébrak et al. (2017)
    • Centre-du-Québec
      • Arthabaska RCM
        • Saints-Martyrs-Canadiens
Williams-Jones et al. (1997)
  • Yukon
    • Whitehorse mining district
      • Wheaton River District
        • Carbon Hill
Peatfield (n.d.)
China
 
  • Guangxi
    • Hechi
      • Nandan County
Chen Dianfen et al. (1985) +2 other references
    • Hezhou
      • Zhongshan Co.
        • Guposhan Sn-polymetallic ore field
          • Wanggao ore field
Yi Li and Lairen Lai (1993)
Yi Li and Lairen Lai (1993)
  • Guizhou
    • Qiandongnan
      • Kaili County
Yongke Chen et al. (2004)
  • Hunan
    • Chenzhou
      • Yizhang Co.
        • Yaogangxian W-Sn ore field
Ottens (2011) +1 other reference
  • Inner Mongolia
    • Xilingol League (Xilinguole Prefecture)
      • Sonid Left Banner (Sunite Zuoqi)
Mei Zhang et al. (2011)
  • Qinghai
    • Haixi Mongol and Tibetan Autonomous Prefecture
      • Dulan County
        • Wulonggou gold field
          • Shenshuitan Au deposit
Houmin Li et al. (2001) +2 other references
  • Xinjiang
    • Kezilesu Autonomous Prefecture (Kizilsu Autonomous Prefecture; Qizilsu Autonomous Prefecture)
      • Wuqia Co. (Ulugqat Co.; Ulughchat Co.)
Minghua Zheng et al. (2002) +1 other reference
Czech Republic
 
  • Central Bohemian Region
    • Kladno District
Žáček
    • Kutná Hora District
      • Kutná Hora
Pauliš P. Mineralogické lokality ...
Macků
    • Příbram District
Mrázek
      • Lešetice
Litochleb
Litochleb et al. (2011)
      • Příbram
        • Bohutín
          • Bohutín deposit
[Bull.N.M.Praha 2002
  • Olomouc Region
    • Šumperk District
      • Staré Město
        • Hynčice pod Sušinou
Fojt +8 other references
  • Plzeň Region
    • Klatovy District
Litochleb J. et al. (Šumava, Česká republika)
    • Plzeň-North District
Pauliš et al. (2019)
Veselovský (2019)
Pašava et al. (1993) +1 other reference
    • Plzeň-South District
Litochleb (jz. Čechy) +1 other reference
  • Vysočina Region
Mederski et al. (2020)
Finland
 
  • Lapland
    • Kittilä
Kojonen et al. (2008)
  • North Ostrobothnia
    • Raahe
Sergeeva et al. (2011, February)
  • South Ostrobothnia
    • Seinäjoki
Geological Survey of Finland website +2 other references
Aho +1 other reference
Borodaev et al. (1983)
France
 
  • Auvergne-Rhône-Alpes
    • Allier
      • Vichy
        • Nades
          • Nades mines
J.-J. Périchaud: Les Minéraux d'Auvergne et al. (1985) +1 other reference
    • Cantal
      • Mauriac
R. Pierrot
R. Pierrot
      • Saint-Flour
        • Leyvaux
          • Le Breuil
Pierrot et al. (1971) +1 other reference
R. Pierrot
R. Pierrot
R. Pierrot
        • Massiac
Fermis (2022)
        • Molèdes
R. Pierrot
        • Saint-Mary-le-Plain
          • Espezolles
            • Anval farm
R. Pierrot
Belot (1978) +1 other reference
R. Pierrot
Belot (1978)
R. Pierrot
        • Talizat
          • Auliac
J.-J. Périchaud: "Les Minéraux ... +1 other reference
        • Védrines-Saint-Loup
    • Haute-Loire
      • Brioude
        • Ally
Sebastian Axt Collection
          • La Licoulne
Pélisson (1989)
Pélisson (1989)
          • La Rodde mine
Périchaud (1968)
Périchaud (1968)
        • Blesle
          • Le Cheylat
            • La Vialle
www.brgm.fr (2003)
www.brgm.fr (2003)
www.brgm.fr (2003)
Périchaud (1968)
        • Chazelles
Pélisson (1989)
        • Langeac
          • Barlet
Pélisson (1989)
Pélisson (1989)
        • Lubilhac
          • Dahu Mine (Daü Mine; Dahut Mine)
C. Vialaron : La mine d'antimoine de Daü et al. (1999)
C. Vialaron : La mine d'antimoine de Daü et al. (1999)
Périchaud (1968)
        • Mercœur
J.-J. Périchaud: Les Minéraux d'Auvergne et al. (1986)
        • Saint-Beauzire
Pélisson (1989)
        • Saint-Cirgues
Pélisson (1989)
        • Saint-Just-près-Brioude
Pélisson (1989)
          • Ladignat
Périchaud (1968)
Belot (1978)
        • Saint-Pal-de-Senouire
Pélisson (1989)
        • Torsiac
          • Lanau
Périchaud (1968) +1 other reference
            • Marmaissat
Périchaud (1968) +1 other reference
Périchaud (1968) +1 other reference
Périchaud (1968) +1 other reference
Périchaud (1968) +1 other reference
Périchaud (1968) +1 other reference
Périchaud (1968) +1 other reference
Périchaud (1968) +1 other reference
        • Vieille-Brioude
Pélisson (1989)
      • Saint-Just-près-Brioude
Edinburgh. Journ of Science (1827)
Périchaud (1968)
    • Loire
      • Saint-Étienne
        • Saint-Héand
BRGM - Fiche BSS 07451X4001
        • Saint-Joseph
BRGM (1981)
    • Puy-de-Dôme
      • Issoire
        • Anzat-le-Luguet
J.-J. Périchaud: Les Minéraux d'Auvergne et al. (1985)
        • Singles
Marcoux et al. (1988)
      • Riom
        • Pontgibaud
          • Massagette
Y. Blanc : "Datation par analyse ...
  • Brittany
    • Finistère
      • Morlaix
        • Plouvorn
Pierrot et al. (1973)
      • Quimper
        • Audierne
          • Esquibien
Y. Moëlo
Y. Fouquet
        • Ergué-Gabéric
Pierrot et al. (1973)
Pierrot et al. (1973)
        • Plogoff
Y. Fouquet
        • Quimper
Chauris (2014)
    • Ille-et-Vilaine
      • Fougères-Vitré
        • Martigné-Ferchaud
Pillard F. et al. (1985) +1 other reference
  • Corsica
    • Haute-Corse
      • Bastia
        • Meria
Aicard et al. (1977)
Y. Moëlo
  • Grand Est
    • Bas-Rhin
      • Sélestat-Erstein
        • Lalaye
          • Charbes
Wittern et al. (1997)
Hohl (1994)
Hohl (1994)
  • Nouvelle-Aquitaine
    • Creuse
      • Aubusson
        • Budelière
Bull. Soc. Franç. Minér. Crist. +1 other reference
        • Mérinchal
Thiery et al. (2020)
        • Saint-Dizier-la-Tour
Gatellier et al. (1990)
    • Haute-Vienne
      • Limoges
        • Glandon
Queneau (n.d.) +1 other reference
        • La Roche-l'Abeille
Limoges University
  • Occitanie
    • Hérault
      • Béziers
        • Ceilhes-et-Rocozels
Munoz M (1981)
    • Lozère
      • Florac
        • Saint-Germain-de-Calberte
          • St Etienne-Vallée-Française
Inventaire Minéralogique de la France Numéro 14 ( Lozère )
    • Pyrénées-Orientales
      • Céret
        • Oms
          • Oms (south-west) antimony occurrence
Guitard (2010)
  • Pays de la Loire
    • Vendée
      • La Roche-sur-Yon
        • Chavagnes-en-Paillers
Lemière +8 other references
        • Les Brouzils
Lemière +8 other references
  • Provence-Alpes-Côte d'Azur
    • Var
      • Toulon
        • La Londe-les-Maures
          • Les Bormettes district
Mari et al. (1979)
          • Valcros
Mari et al. (1979)
Mari et al. (1979)
Mari et al. (1979)
Mari et al. (1979)
Mari et al. (1979)
Georgia
 
  • Racha-Lechkhumi and Kvemo Svaneti
    • Oni District
Kekelia et al. (2008)
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Breisgau-Hochschwarzwald
        • Bollschweil
          • St Ulrich
Walenta (1992)
Walenta (1992) +1 other reference
        • Glottertal
Walenta (1992)
        • Münstertal
          • St Trudpert
Walenta (1992)
        • Sulzburg
Walenta (1992)
      • Emmendingen
        • Waldkirch
          • Suggental
Walenta (1992)
      • Ortenaukreis
        • Haslach im Kinzigtal
          • Fischerbach
          • Haslach im Kinzigtal
Lapis 1985 (11)
          • Steinach
            • Welschensteinach
Weiß (1990)
  • Bavaria
    • Upper Franconia
      • Bayreuth District
Knauer et al. (1968) +1 other reference
  • Lower Saxony
    • Goslar District
      • Braunlage
  • North Rhine-Westphalia
    • Arnsberg
      • Hochsauerlandkreis
        • Arnsberg
          • Uentrop
Bindi et al. (2005)
  • Rhineland-Palatinate
    • Ahrweiler
      • Altenahr
        • Ahrbrück
          • Martinsknipp
Beyer (1978)
    • Donnersbergkreis
      • Nordpfälzer Land
        • Obermoschel
Lapis 2001 (6)
    • Neuwied
      • Puderbach
        • Raubach
Schnorrer (1993)
  • Saxony
Hofmann (1992)
    • Erzgebirgskreis
      • Drebach
minmax.net (n.d.)
      • Thum
Haake (1998)
    • Mittelsachsen
      • Großschirma
        • Kleinvoigtsberg
Frenzel (1874)
      • Oberschöna
Loczka (1903)
Gerstenberg (n.d.)
Enrico Bonacina
Naumann et al. (1898)
      • Reinsberg
        • Hirschfeld
Gerstenberg (n.d.)
    • Vogtlandkreis
      • Schöneck
        • Kottenheide
Tröger (2012)
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Plaka
          • Plaka Mines
Rieck et al. (1999)
  • Central Macedonia
    • Kilkis
      • Kilkis
Kanellopoulos et al. (2024)
Evaggelos Skoupras et al. (2022)
    • Thessaloniki
      • Lagkadas
Kanellopoulos et al. (2024)
  • North Aegean
    • Chios
      • Chios
Tzamos +9 other references
Hungary
 
  • Heves County
    • Gyöngyös District
      • Mátraszentimre
Szakáll et al. (1996)
Indonesia
 
  • Central Kalimantan Province
    • Muller Mountains
www.turnstone.ca (2002)
Italy
 
  • Aosta Valley
    • Courmayeur
      • Sapin Valley
Paolo Castello: Lo Ialofane e gli altri minerali del giacimento piombo-baritico del Trou des Romains (Courmayeur, Valle d'Aosta) +1 other reference
  • Lombardy
    • Como Province
      • San Nazzaro Val Cavargna
- (n.d.)
    • Lecco Province
      • Vendrogno
- (n.d.)
    • Sondrio Province
      • Sondalo
Bedognè et al. (2006)
    • Varese Province
      • Cadegliano-Viconago
- (n.d.)
  • Piedmont
    • Metropolitan City of Turin
      • Valprato Soana
        • Campiglia Soana
Piccoli et al. (2007)
  • Sardinia
    • Nuoro Province
      • Gadoni
Stara et al. (1999)
De Michele (1974)
    • Sassari Province
      • Sassari
Ara D. et al. (2013)
    • South Sardinia Province
      • Burcei
Stara et al. (1993)
      • Muravera
Traverso (1898) +2 other references
      • San Vito
Piepoli (1933) +1 other reference
Piepoli (1933) +1 other reference
Piepoli (1933) +1 other reference
  • Trentino-Alto Adige (Trentino-South Tyrol)
    • Trento Province
      • Sant'Orsola Terme
        • Mala
Burtet Fabris B. (1994)
  • Tuscany
    • Grosseto Province
      • Gavorrano
Capperi M.
      • Massa Marittima
        • Montoccoli-Castellaccia area (Fosso Zanca-Filone di Montoccoli area; Zanca Valley mines)
Bazzoni C. et al. (2011)
- (n.d.) +1 other reference
      • Scansano
Brizzi G. & Meli R. (1995)
    • Livorno Province
      • Campiglia Marittima
Biagioni et al. (2014)
Biagioni C. et al. (2014)
    • Pisa Province
      • Pomarance
Duchi G. (Comune di Pomarance, Pisa) +1 other reference
Japan
 
  • Aichi Prefecture
    • Kitashitara County
      • Toei
Yamada (2004)
Dr Ryuji Marumoto collection
  • Fukuoka Prefecture
    • Tagawa District
      • Kawara
Uehara et al. (2014)
Yamada (2004)
  • Gifu Prefecture
    • Shirakawamura
- (n.d.)
  • Gunma Prefecture
    • Shimonita
 ...
  • Hokkaidō Prefecture
    • Ishikari Subprefecture
      • Sapporo City
        • Minami-ku
矢島淳吉 (1979) +1 other reference
  • Hyogo Prefecture
    • Yabu City
      • Sekinomiya-machi
- (n.d.) +3 other references
  • Kagoshima Prefecture
    • Hioki City
      • Fukiage
University of Tokyo collection
- (n.d.)
    • Suzuyama mining district
- (n.d.)
  • Miyazaki Prefecture
University of Tokyo collection
  • Nagano Prefecture
    • Shimoina District
- (n.d.)
  • Oita Prefecture
    • Hayami District
- (n.d.)
      • Yamaga
- (n.d.)
  • Shizuoka Prefecture
    • Hamamatsu City
      • Tenryuu-ku
        • Sakuma-cho
          • Kune mine
- (n.d.)
Kazakhstan
 
  • Abai Region
    • Semey
Kovalev et al. (2009)
  • Akmola Region
    • Stepnogorsk
      • Aksu (Aqsu)
Pekov (1998) +2 other references
  • East Kazakhstan Region
    • Altai District
      • Zyryanovsk complex
Mozgova et al. (1994)
    • Katonkaragay District
Mozgova et al. (1994)
Kosovo
 
  • Pristina District
    • Graçanica
      • Badoc
Mederski et al. (2021) +1 other reference
      • Gračanica (Graçanicë)
Mederski et al. (2019)
Kyrgyzstan
 
  • Osh Region
Nikonorov et al. (2004)
Luxembourg
 
  • Canton Wiltz
    • Goesdorf
Philippo et al. (2007) +1 other reference
Mali
 
  • Kayes Region
    • Kayes Cercle
Masurel et al. (2017)
      • Sadiola Commune
Masurel (2016) +1 other reference
Mexico
 
  • Baja California Sur
    • La Paz Municipality
      • El Triunfo District
Panczner (1987)
Panczner (1987)
Panczner (1987)
Panczner (1987)
Panczner (1987)
Panczner (1987)
Panczner (1987)
Panczner (1987)
Panczner (1987)
Panczner (1987)
Panczner (1987)
      • San Antonio District
Panczner (1987)
  • Durango
    • Indé Municipality
      • Indé
Panczner (1987)
  • Mexico
    • Temascaltepec Municipality
Rubinovich-Kogan et al. (1988) +1 other reference
  • Zacatecas
    • Noria de Ángeles Municipality
      • Noria de Angeles (Noria de los Angeles)
Panczner (1987)
Panczner (1987)
    • Sombrerete Municipality
      • San Martín
        • San Martín-Sabinas District
RWMW specimen
North Macedonia
 
  • Kavadarci Municipality
    • Ržanovo
Boev et al. (1993)
  • Kriva Palanka Municipality
Mudrinic et al. (1997)
Norway
 
  • Troms og Finnmark
    • Karlsøy
- (n.d.) +1 other reference
Carstens (1937) +1 other reference
  • Trøndelag
    • Hitra
      • Hitra Island
        • Melandsjø mining field
Larsen (2019)
Peru
 
  • Puno
    • Carabaya Province
Aguirre Cernades (2017)
Poland
 
  • Lower Silesian Voivodeship
    • Kamienna Góra County
      • Gmina Kamienna Góra
        • Czarnów
Mochnacka et al. (2009) +1 other reference
Portugal
 
  • Beja
    • Beja
      • Nossa Senhora das Neves
Mateus et al. (2005)
    • Mértola
      • São Pedro de Solis e São Sebastião dos Carros
Mateus
  • Bragança
    • Bragança
      • Outeiro
LNEG - Laboratório Nacional de Energia ...
    • Mirandela
      • Mascarenhas
LNEG - Laboratório Nacional de Energia ...
  • Porto
    • Gondomar
      • Lomba
LNEG - Laboratório Nacional de Energia ...
      • Medas
      • Melres
    • Penafiel
      • Lagares e Figueira
LNEG - Laboratório Nacional de Energia ...
Romania
 
  • Alba County
    • Roșia Montană
www.gl.rhbnc.ac.uk (2003)
  • Maramureș County
    • Baia Mare
Zsivny et al. (1934) +1 other reference
    • Baia Sprie
link dead +1 other reference
Marias Francisc
    • Cavnic
Cooper (1992)
Szakáll (2002)
Russia
 
  • Chukotka Autonomous Okrug
    • Anadyrsky District
Savva et al. (2012)
  • Kemerovo Oblast
    • Belovsky District
Bortnikova et al. (2017)
  • Krasnoyarsk Krai
    • Enisei Range (Yenisei Ridge; Enisei Ridge)
Afanas'eva et al. (1995) +4 other references
Borisenko et al. (2014)
Borisenko et al. (2014)
Genkin et al. (1998)
Kovalev et al. (2023)
Seltmann et al. (2010)
    • Severo-Yeniseysky District
Onufrienok et al. (2015)
Seltmann et al. (2010)
  • Magadan Oblast
    • Arik-Revkom zone
Pekov (1998)
  • Nenets Autonomous Okrug
    • Zapolyarny Municipal District (Zapolyarny District)
      • Kanin Peninsula
geo.web.ru (2012)
  • Republic of Karelia
    • Pitkyarantsky District
      • Alattu-Pakula-Janis ore field
Ivashchenko (2024)
  • Sakha
    • Aldansky District
      • Upper Amga gold-mining district
Anisimova et al. (2020)
          • Verkhneamginskaya auriferous zone
Kasatkin et al. (2022)
Goryachev et al. (2011)
    • Indigirka River Basin
      • Sana-Maltan ore field
Fridovsky et al. (2014)
Seltmann et al. (2010)
    • Sarychev Range
Gamyanin G.N. et al. (2001)
    • Tyry River
Bortnikov et al. (2007)
    • Verkhoyansk District
Pal’yanova et al. (2016)
  • Zabaykalsky Krai
    • Nerchinsky District
      • Adun-Cholon Range
Kasatkin et al. (2014)
Serbia
 
  • Central Serbia
    • Moravica District
      • Ivanjica
Ministry of Mining and Energy (2002)
Slovakia
 
  • Banská Bystrica Region
    • Banská Bystrica District
Koděra (1986)
    • Brezno District
      • Brezno
Koděra (1986)
Hoppanová et al. (2023)
      • Bystrá
Majzlan (1996)
      • Dolná Lehota
Koděra (1986)
      • Jasenie
Koděra (1986)
    • Poltár District
Maťo et al. (stredné Slovensko)
    • Revúca District
      • Chyžné
Bálintová T. et al. (Slovakia)
Koděra (1986)
    • Rimavská Sobota District
      • Klenovec
Ferenc Š. (2015)
  • Bratislava Region
    • Malacky District
      • Kuchyňa
      • Pernek
Sejkora et al. (2007)
    • Pezinok District
      • Častá
Koděra (1986)
      • Limbach
Andráš P. et al. (1999)
      • Pezinok
Dill (1998) +1 other reference
Ozdín D.
Ozdín D.
Chovan M. +1 other reference
  • Košice Region
    • Gelnica District
Koděra (1986)
      • Helcmanovce
Koděra (1986)
Koděra (1986)
      • Smolnícka Huta
Koděra (1986)
      • Smolník
Koděra (1986)
Grecula (1995)
Koděra (1986)
    • Košice-okolie District
      • Opátka
Koděra (1986)
      • Poproč
Koděra (1986)
Grecula (1995)
Koděra (1986)
Martin Števko-unpublished
Pauliš et al. (2002)
Grecula (1995)
    • Rožňava District
      • Betliar
Koděra (1986) +1 other reference
      • Čučma
Koděra (1986)
      • Rožňava
Koděra (1986)
        • Mária Mine
Mikuš T. et al. (2018)
  • Prešov Region
    • Poprad District
      • Štrba
        • Štrbské Pleso
Bakoš F. et al. (Tatry) +1 other reference
      • Vysoké Tatry
Makovicky et al. (2007)
    • Prešov District
      • Červenica
        • Dubník
Koděra (1986)
      • Zlatá Baňa
Duda et. all.
Koděra (1986)
Ďuďa R. (2001)
  • Trenčín Region
    • Prievidza District
      • Chvojnica
Mikuš et al. (2003)
  • Žilina Region
    • Liptovský Mikuláš District
      • Nižná Boca
        • Nižná Boca antimony-gold deposit
Smirnov A. (Nízke Tatry)
      • Partizánska Ľupča
Chovan et al. (1995)
Smirnov et al. (2007)
South Africa
 
  • Limpopo
    • Mopani District Municipality
      • Ba-Phalaborwa Local Municipality
        • Murchison Range
          • Gravelotte
            • Consolidated Murchison Mines
Cairncross et al. (1995) +1 other reference
Cairncross et al. (1995)
Williams-Jones et al. (1997)
    • Waterberg District Municipality
      • Mogalakwena Local Municipality
        • Mokopane
Hutchinson et al. (2005)
  • Mpumalanga
    • Ehlanzeni District Municipality
      • Mbombela Local Municipality
Cairncross et al. (1995)
South Korea
 
  • North Gyeongsang Province
    • Bonghwa County
Yun et al. (1999)
  • South Gyeongsang Province
    • Jinju City
Choi (1998)
Spain
 
  • Andalusia
    • Córdoba
      • Espiel
Gumiel (1983)
    • Jaén
Lillo Ramos (1992)
  • Castile-La Mancha
    • Ciudad Real
      • Almuradiel
Calvo (2003)
  • Castile and Leon
    • León
      • Maraña
        • Boicibacar
Luque et al. (1989)
        • Puerto de las Señales
Martín-Izard et al. (2009)
  • Catalonia
    • Girona
      • Pardines
      • Ribes de Freser
Bull. Minéral.
  • Community of Madrid
    • Montejo de la Sierra
Jiménez Martínez
  • Extremadura
    • Badajoz
      • Alburquerque
Gumiel et al. (1976)
Sweden
 
  • Örebro County
    • Hällefors
  • Västerbotten County
    • Malå
Jonsson (1992)
Switzerland
 
  • Ticino
    • Lugano
Stalder et al. (1998)
Schmutz et al. (1986)
Meisser N. et al. (2020)
  • Valais
    • Saint-Maurice
      • Collonges
        • Plex
Stalder et al. (1998)
Tajikistan
 
  • Sughd
    • Mastchoh District
      • Altyn-Topkan ore field (Zarnisor ore field)
Badalov et al. (1975)
Badalov et al. (1975)
UK
 
  • England
    • Cornwall
      • St Endellion
        • Port Isaac
Golley et al. (1995)
Golley et al. (1995)
    • Cumbria
      • Allerdale
        • Caldbeck
          • Coombe Height
Fortey et al. (1984) +1 other reference
Stanley et al. (1991)
      • Eden
        • Patterdale
          • Hartsop
Day (1999)
Ukraine
 
  • Crimea
Golubovskaya (2001)
USA
 
  • California
    • Kern County
      • Boron
Pemberton et al. (1960) +5 other references
Morgan et al. (1969) +2 other references
    • Plumas County
      • Last Chance Mining District
        • Adams Peak
Dunning et al. (2005)
  • Colorado
    • Gunnison County
      • Vulcan Mining District (Cebolla Mining District; Domingo Mining District)
        • Vulcan
Dana 7:I:199
  • Nevada
Castor et al. (2004)
    • Humboldt County
      • National Mining District
Vikre (1985) +1 other reference
  • New Jersey
    • Sussex County
      • Ogdensburg
        • Sterling Hill
Palache +2 other references
  • Washington
    • Chelan County
      • Leavenworth Mining District
        • Van Epps Pass
Cannon (1975)
Cannon (1975)
    • Snohomish County
      • Darrington Mining District
        • Whitehorse Mountain
Cannon (1975)
  • Wyoming
    • Albany County
Hausel et al. (2001)
Uzbekistan
 
  • Samarqand
    • North Nuratau Mountains
      • Zarmitan
Bortnikov et al. (1996)
Vietnam
 
  • Hà Giang Province
    • Yên Minh District
Shunso Ishihara and Pham Tich Xuan (2013)
  • Tuyên Quang Province
    • Lang Vai mining district
Nevolko et al. (2019)
Zimbabwe
 
  • Matabeleland South
    • Gwanda - Filabusi District
Saager et al. (1987)
  • Midlands
    • Kwekwe District
Zeitschrift fuer angewandte Geologie 38 (1992)
    • Mberengwa District
      • Sandawana-Belingwe District
Zeitschrift fuer angewandte Geologie 38 (1992)
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