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Brookhart, M., Volpe, A. F., Lincoln, D. M., Horvath, I. T., Millar, J. M. (1990) Detection of an alkyl ethylene complex during ethylene polymerization by a cobalt(III) catalyst. Energetics of the .beta.-migratory insertion reaction. Journal Of The American Chemical Society, 112 (14) 5634-5636 doi:10.1021/ja00170a035

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Reference TypeJournal (article/letter/editorial)
TitleDetection of an alkyl ethylene complex during ethylene polymerization by a cobalt(III) catalyst. Energetics of the .beta.-migratory insertion reaction
JournalJournal Of The American Chemical Society
AuthorsBrookhart, M.Author
Volpe, A. F.Author
Lincoln, D. M.Author
Horvath, I. T.Author
Millar, J. M.Author
Year1990 (July)Volume112
Issue14
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja00170a035Search in ResearchGate
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Mindat Ref. ID1441707Long-form Identifiermindat:1:5:1441707:0
GUID0
Full ReferenceBrookhart, M., Volpe, A. F., Lincoln, D. M., Horvath, I. T., Millar, J. M. (1990) Detection of an alkyl ethylene complex during ethylene polymerization by a cobalt(III) catalyst. Energetics of the .beta.-migratory insertion reaction. Journal Of The American Chemical Society, 112 (14) 5634-5636 doi:10.1021/ja00170a035
Plain TextBrookhart, M., Volpe, A. F., Lincoln, D. M., Horvath, I. T., Millar, J. M. (1990) Detection of an alkyl ethylene complex during ethylene polymerization by a cobalt(III) catalyst. Energetics of the .beta.-migratory insertion reaction. Journal Of The American Chemical Society, 112 (14) 5634-5636 doi:10.1021/ja00170a035
In(1990, July) Journal Of The American Chemical Society Vol. 112 (14) American Chemical Society (ACS)

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Rix, Francis C., Brookhart, Maurice (1995) Energetics of Migratory Insertion Reactions in Pd(II) Acyl Ethylene, Alkyl Ethylene, and Alkyl Carbonyl Complexes. Journal Of The American Chemical Society, 117 (3) 1137-1138 doi:10.1021/ja00108a034
Brookhart, M., Lincoln, D. M. (1988) Comparison of migratory aptitudes of hydride and alkyl groups in .beta.-migratory insertion reactions of Cp*(P(OMe)3)Rh(C2H4)R+ (R = H, CH2CH3) Journal Of The American Chemical Society, 110 (26) 8719-8720 doi:10.1021/ja00234a036
Tanner, Martha J., Brookhart, M., DeSimone, J. M. (1997) Observation of an Inverse Kinetic Isotope Effect in a Co(III)-Catalyzed Polymerization of Ethylene. Journal Of The American Chemical Society, 119 (32) 7617-7618 doi:10.1021/ja971300s
Burger, Barbara J., Thompson, Mark E., Cotter, W. Donald, Bercaw, John E. (1990) Ethylene insertion and .beta.-hydrogen elimination for permethylscandocene alkyl complexes. A study of the chain propagation and termination steps in Ziegler-Natta polymerization of ethylene. Journal Of The American Chemical Society, 112 (4) 1566-1577 doi:10.1021/ja00160a041
Schmidt, Gregory F., Brookhart, Maurice (1985) Implications of three-center, two-electron M--H--C bonding for related alkyl migration reactions: design and study of an ethylene polymerization catalyst. Journal Of The American Chemical Society, 107 (5) 1443-1444 doi:10.1021/ja00291a073
Brookhart, Maurice, Hauptman, Elisabeth, Lincoln, David M. (1992) .beta.-Migratory insertion reactions of (.eta.5-C5R'5)Rh(L)(C2H4)R+BF4- (R' = hydrogen, methyl; R = hydrogen, ethyl; L = P(OMe)3, PMe3) Comparison of the energetics of hydride versus alkyl migration. Journal Of The American Chemical Society, 114 (26) 10394-10401 doi:10.1021/ja00052a040
Small, Brooke L., Brookhart, Maurice, Bennett, Alison M. A. (1998) Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene. Journal Of The American Chemical Society, 120 (16) 4049-4050 doi:10.1021/ja9802100
Brookhart, M., DeSimone, J. M., Grant, B. E., Tanner, M. J. (1995) Cobalt(III)-Catalyzed Living Polymerization of Ethylene: Routes to End-Capped Polyethylene with a Narrow Molar Mass Distribution. Macromolecules, 28. 5378-5380 doi:10.1021/ma00119a033
Evitt, Eric R., Bergmann, Robert G. (1979) Reaction of a metal alkyl with ethylene as a model for Ziegler-Natta polymerization. Evidence for the olefin insertion mechanism. Journal Of The American Chemical Society, 101 (14) 3973-3974 doi:10.1021/ja00508a049
Hoover, James F., Stryker, Jeffrey M. (1990) Coupling of a 2-oxacyclopentylidene and a phosphonium ylide ligand at platinum. Migratory insertion of a Fischer carbene into a metal alkyl bond. Journal Of The American Chemical Society, 112 (1) 464-465 doi:10.1021/ja00157a080
Burke, M. L., Madix, R. J. (1991) Migratory insertion of ethylene into iron-hydrogen bonds and .beta.-hydride elimination of ethyl groups on hydrogen-covered iron(100) Journal Of The American Chemical Society, 113 (10) 3675-3684 doi:10.1021/ja00010a007
 
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