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Burger, Barbara J., Thompson, Mark E., Cotter, W. Donald, Bercaw, John E. (1990) Ethylene insertion and .beta.-hydrogen elimination for permethylscandocene alkyl complexes. A study of the chain propagation and termination steps in Ziegler-Natta polymerization of ethylene. Journal Of The American Chemical Society, 112 (4) 1566-1577 doi:10.1021/ja00160a041

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Reference TypeJournal (article/letter/editorial)
TitleEthylene insertion and .beta.-hydrogen elimination for permethylscandocene alkyl complexes. A study of the chain propagation and termination steps in Ziegler-Natta polymerization of ethylene
JournalJournal Of The American Chemical Society
AuthorsBurger, Barbara J.Author
Thompson, Mark E.Author
Cotter, W. DonaldAuthor
Bercaw, John E.Author
Year1990 (February)Volume112
Issue4
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja00160a041Search in ResearchGate
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Mindat Ref. ID1446345Long-form Identifiermindat:1:5:1446345:9
GUID0
Full ReferenceBurger, Barbara J., Thompson, Mark E., Cotter, W. Donald, Bercaw, John E. (1990) Ethylene insertion and .beta.-hydrogen elimination for permethylscandocene alkyl complexes. A study of the chain propagation and termination steps in Ziegler-Natta polymerization of ethylene. Journal Of The American Chemical Society, 112 (4) 1566-1577 doi:10.1021/ja00160a041
Plain TextBurger, Barbara J., Thompson, Mark E., Cotter, W. Donald, Bercaw, John E. (1990) Ethylene insertion and .beta.-hydrogen elimination for permethylscandocene alkyl complexes. A study of the chain propagation and termination steps in Ziegler-Natta polymerization of ethylene. Journal Of The American Chemical Society, 112 (4) 1566-1577 doi:10.1021/ja00160a041
In(1990, February) Journal Of The American Chemical Society Vol. 112 (4) American Chemical Society (ACS)

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Piers, Warren E., Bercaw, John E. (1990) .alpha. Agostic assistance in Ziegler-Natta polymerization of olefins. Deuterium isotopic perturbation of stereochemistry indicating coordination of an .alpha. carbon-hydrogen bond in chain propagation. Journal Of The American Chemical Society, 112 (25) 9406-9407 doi:10.1021/ja00181a060
Hajela, Sharad, Bercaw, John E. (1994) Competitive Chain Transfer by .beta.-Hydrogen and .beta.-Methyl Elimination for a Model Ziegler-Natta Olefin Polymerization System [Me2Si(.eta.5-C5Me4)2]Sc{CH2CH(CH3)2}(PMe3). Organometallics, 13. 1147-1154 doi:10.1021/om00016a018
Thompson, Mark E., Baxter, Steven M., Bulls, A. Ray, Burger, Barbara J., Nolan, Michael C., Santarsiero, Bernard D., Schaefer, William P., Bercaw, John E. (1987) .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds. Journal Of The American Chemical Society, 109 (1) 203-219 doi:10.1021/ja00235a031
Evitt, Eric, Bergman, Robert (1980) Additions and Corrections - Reaction of a Metal Alkyl with Ethylene as a Model for Ziegler-Natta Polymerization. Evidence for the Olefin Insertion Mechanism. Journal Of The American Chemical Society, 102 (2) 891 doi:10.1021/ja00522a605
Bunel, Emilio., Burger, Barbara J., Bercaw, John E. (1988) Carbon-carbon bond activation via .beta.-alkyl elimination. Reversible branching of 1,4-pentadienes catalyzed by scandocene hydride derivatives. Journal Of The American Chemical Society, 110 (3) 976-978 doi:10.1021/ja00211a053
Evitt, Eric R., Bergmann, Robert G. (1979) Reaction of a metal alkyl with ethylene as a model for Ziegler-Natta polymerization. Evidence for the olefin insertion mechanism. Journal Of The American Chemical Society, 101 (14) 3973-3974 doi:10.1021/ja00508a049
Brookhart, M., Volpe, A. F., Lincoln, D. M., Horvath, I. T., Millar, J. M. (1990) Detection of an alkyl ethylene complex during ethylene polymerization by a cobalt(III) catalyst. Energetics of the .beta.-migratory insertion reaction. Journal Of The American Chemical Society, 112 (14) 5634-5636 doi:10.1021/ja00170a035
Leatherman, Mark D., Svejda, Steven A., Johnson, Lynda K., Brookhart, Maurice (2003) Mechanistic Studies of Nickel(II) Alkyl Agostic Cations and Alkyl Ethylene Complexes:  Investigations of Chain Propagation and Isomerization in (α-diimine)Ni(II)-Catalyzed Ethylene Polymerization. Journal Of The American Chemical Society, 125 (10) 3068-3081 doi:10.1021/ja021071w
Coughlin, E. Bryan, Bercaw, John E. (1992) Iso-specific Ziegler-Natta polymerization of .alpha.-olefins with a single-component organoyttrium catalyst. Journal Of The American Chemical Society, 114 (19) 7606-7607 doi:10.1021/ja00045a068
Burger, Barbara J., Santarsiero, Bernard D., Trimmer, Mark S., Bercaw, John E. (1988) Kinetics and mechanism of the insertion of olefins into niobium- and tantalum-hydride bonds: a study of the competition between steric and electronic effects. Journal Of The American Chemical Society, 110 (10) 3134-3146 doi:10.1021/ja00218a023
Bierwagen, Erik P., Bercaw, John E., Goddard, W. A. (1994) Theoretical Studies of Ziegler-Natta Catalysis: Structural Variations and Tacticity Control. Journal Of The American Chemical Society, 116 (4) 1481-1489 doi:10.1021/ja00083a037
 
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