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Starova, G. L., Filatov, S. K., Matusevich, G. L., Fundamensky, V. S. (1995) The crystal structure of vlodavetsite, AlCa2(SO4)2F2Cl·4H2O. Mineralogical Magazine, 59 (394) 159-162 doi:10.1180/minmag.1995.59.394.16

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Reference TypeJournal (article/letter/editorial)
TitleThe crystal structure of vlodavetsite, AlCa2(SO4)2F2Cl·4H2O
JournalMineralogical MagazineISSN0026-461X
AuthorsStarova, G. L.Author
Filatov, S. K.Author
Matusevich, G. L.Author
Fundamensky, V. S.Author
Year1995 (March)Volume59
Issue394
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_59/59-394-159.pdf+
DOIdoi:10.1180/minmag.1995.59.394.16Search in ResearchGate
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Mindat Ref. ID2622Long-form Identifiermindat:1:5:2622:6
GUID0
Full ReferenceStarova, G. L., Filatov, S. K., Matusevich, G. L., Fundamensky, V. S. (1995) The crystal structure of vlodavetsite, AlCa2(SO4)2F2Cl·4H2O. Mineralogical Magazine, 59 (394) 159-162 doi:10.1180/minmag.1995.59.394.16
Plain TextStarova, G. L., Filatov, S. K., Matusevich, G. L., Fundamensky, V. S. (1995) The crystal structure of vlodavetsite, AlCa2(SO4)2F2Cl·4H2O. Mineralogical Magazine, 59 (394) 159-162 doi:10.1180/minmag.1995.59.394.16
In(1995, March) Mineralogical Magazine Vol. 59 (394) Mineralogical Society
Abstract/NotesAbsractThe crystal structure of vlodavetsite, AlCa2(SO4)2F2Cl·4H2O, has been determined, space group I4/m, a = 6.870(1), c = 13.342(2) Å, Z = 2, Dx = 2.35 g/cm3. The polyhedron cation chains are parallel to [001] and consist of couples of distorted Ca octahedra alternating with one distorted Al octahedron rotated through 24° with respect to the former. The chains are linked by SO4-tetrahedra so that all of the four tetrahedron oxygen atoms take part in coordination of Ca atoms to form a distorted octahedron with Cl and F atoms. The Al coordination polyhedron consists of two F atoms and four oxygen atoms belonging to water molecules. There is a specific interaction via hydrogen bonds between oxygen atoms of SO4-tetrahedra and water molecules.

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Starova, G.L., Filatov, S.K., Matusevich, G.L., Fundamensky, V.S. (1995) The crystal structure of vlodavetsite, AlCa2(SO4)2F2Cl•4H2O. Mineralogical Magazine: 59: 159–162.
Starova, G. L., Fundamenskiy, V. S., Filatov, S. K., Matusevich, G. L., Vergasova, L. P. (1993) Crystal structure of AlCa2(SO4)2F2Cl.4H2O. Acta Crystallographica Section A Foundations of Crystallography, 49. doi:10.1107/s0108767378092326
Starova, G. L., Filatov, S. K., Fundamensky, V. S., Vergasova, L. P. (1991) The crystal structure of fedotovite, K2Cu3O(SO4)3. Mineralogical Magazine, 55 (381) 613-616 doi:10.1180/minmag.1991.055.381.14
Vergasova, L.P., Filatov, S.K., Starova, G.L., Matusevich, G.L., Filasova, T.M. (1995) Vlodavetsite AlCa2(SO4)2F2Cl•4H2O – a new mineral from volcanic exhalations. Doklady Akademii Nauk SSSR: 343: 358–360.
Vergasova L P, Filatov S K, Starova G L, Matusevich Z L, Filosofova T M (1996) Vlodavetsite, AlCa2(SO4)2F2Cl·4H2O, a new mineral from volcanic exhalations, Transactions (Doklady) of the USSR Academy of Sciences. Earth science sections, 343, 173-176 abstract Am Min 81:768
Vergasova, L.P., Filatov, S.K., Starova, G.L., Matusevich, G.L., Filasova, T.M. (1995) Vlodavetsite AlCa2(SO4)2F2Cl•4H2O – a new mineral from volcanic exhalations. Doklady Akademii Nauk SSSR: 343: 358–360. (in Russian)
Vergasova, L.P., Filatov, S.K., Starova, G.L., Matusevich, Z.L., Filosofova, T.M. (1996) Vlodavetsite, AlCa2(SO4)2F2Cl·4H2O, a new mineral from volcanic exhalations. Transactions (Doklady) of the USSR Academy of Sciences. Earth science sections: 343: 173-176.
Starova, G. L., Krivovlchev, S. V., Fundamensky, V. S., Filatov, S. K. (1997) The crystal structure of averievite, Cu5O2(VO4)2.nMX: comparison with related compounds. Mineralogical Magazine, 61 (406) 441-446 doi:10.1180/minmag.1997.061.406.09
Krivovichev, S. V., Starova, G. L., Filatov, S. K. (1999) ‘Face-to-Face’ relationships between oxocentred tetrahedra and cation-centred tetrahedral oxyanions in crystal structures of minerals and inorganic compounds. Mineralogical Magazine, 63 (2) 263-266 doi:10.1180/minmag.1999.063.2.12
Varaksina, T. V., Fundamensky, V. S., Filatov, S.K., Vergasova, L. P. (1990) The crystal structure of kamchatkite, a new naturally occurring oxychloride sulphate of potassium and copper. Mineralogical Magazine, 54 (377) 613-616 doi:10.1180/minmag.1990.054.377.14
Gorskaya, M. G., Filatov, S. K., Rozhdestvenskaya, I. V., Vergasova, L. P. (1992) The crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, a new mineral from Kamchatka volcanic sublimates. Mineralogical Magazine, 56 (384) 411-416 doi:10.1180/minmag.1992.056.384.14
 
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