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Starova, G. L., Krivovlchev, S. V., Fundamensky, V. S., Filatov, S. K. (1997) The crystal structure of averievite, Cu5O2(VO4)2.nMX: comparison with related compounds. Mineralogical Magazine, 61 (406) 441-446 doi:10.1180/minmag.1997.061.406.09

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Reference TypeJournal (article/letter/editorial)
TitleThe crystal structure of averievite, Cu5O2(VO4)2.nMX: comparison with related compounds
JournalMineralogical MagazineISSN0026-461X
AuthorsStarova, G. L.Author
Krivovlchev, S. V.Author
Fundamensky, V. S.Author
Filatov, S. K.Author
Year1997 (June)Volume61
Issue406
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_61/61-406-441.pdf+
DOIdoi:10.1180/minmag.1997.061.406.09Search in ResearchGate
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Mindat Ref. ID182Long-form Identifiermindat:1:5:182:7
GUID0
Full ReferenceStarova, G. L., Krivovlchev, S. V., Fundamensky, V. S., Filatov, S. K. (1997) The crystal structure of averievite, Cu5O2(VO4)2.nMX: comparison with related compounds. Mineralogical Magazine, 61 (406) 441-446 doi:10.1180/minmag.1997.061.406.09
Plain TextStarova, G. L., Krivovlchev, S. V., Fundamensky, V. S., Filatov, S. K. (1997) The crystal structure of averievite, Cu5O2(VO4)2.nMX: comparison with related compounds. Mineralogical Magazine, 61 (406) 441-446 doi:10.1180/minmag.1997.061.406.09
In(1997, June) Mineralogical Magazine Vol. 61 (406) Mineralogical Society
Abstract/NotesAbstractThe crystal structure of averievite, Cu5O2(VO4)2·nMX has been determined. Trigonal system, space group P3, a = 6.375(1), c = 8.399(1) Å, V = 295.6(1) Å3, Z = 1, Dx = 4.01(1) g/cm3. The atomic arrangement is characterized by infinite nets parallel to (001) composed of [OCu4]6+ tetrahedra linked via corners in hexagonal rings. The bases of neigbouring tetrahedra are in one plane and their non-shared corners are turned to the opposite sides. The [VO4]3− tetrahedra are attached to the bases of [OCu4] tetrahedra. There are large (R >3.2 Å) channels in the structure where large molecular particles can enter. The comparison of the averievite structure with related compounds (in particular, copper oxovanadates) is given from the point of view of [OT4] polyion crystal chemistry.


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